ChemicalBook > CAS DataBase List > 1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE

1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE

Product Name
1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE
CAS No.
38936-60-6
Chemical Name
1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE
Synonyms
O-(4-chlorobenzyl) hydroxylaMine;O-(4-CHLOROBENZYL)HYDROXYLAMINE HCL;4-Chlorobenzyloxyamine hydrochloride;o-(p-chlorobenzyl)-hydroxylaminhydrochloride;O-(4-CHLOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE;O-(p-Chlorobenzyl)hydroxylamine hydrochloride;1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE;1-[(AMINOOXY)METHYL]-4-CHLOROBENZENE HYDROCHLORIDE;O-[(4-chlorophenyl)methyl]Hydroxylamine hydrochloride;1-[(aminooxy)methyl]-4-chlorobenzene hydrochloride (1:1)
CBNumber
CB9734432
Molecular Formula
C7H9Cl2NO
Formula Weight
194.06
MOL File
38936-60-6.mol
More
Less

1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE Property

Melting point:
230°C
form 
solid
color 
White
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HazardClass 
IRRITANT
HS Code 
2921199990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

TRC
Product number
A633675
Product name
1-[(Ammoniooxy)methyl]-4-chlorobenzeneChloride
Packaging
100mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
044741
Product name
1-[(Aminooxy)methyl]-4-chlorobenzene hydrochloride
Purity
>95%
Packaging
500mg
Price
$51
Updated
2021/12/16
Matrix Scientific
Product number
044741
Product name
1-[(Aminooxy)methyl]-4-chlorobenzene hydrochloride
Purity
>95%
Packaging
1g
Price
$79
Updated
2021/12/16
SynQuest Laboratories
Product number
4647-5-X0
Product name
O-(4-Chlorobenzyl)hydroxylamine hydrochloride
Packaging
1g
Price
$184
Updated
2021/12/16
Matrix Scientific
Product number
044741
Product name
1-[(Aminooxy)methyl]-4-chlorobenzene hydrochloride
Purity
>95%
Packaging
5g
Price
$315
Updated
2021/12/16
More
Less

1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE Chemical Properties,Usage,Production

Preparation

To a solution of 83.7 gm (1.5 moles) of potassium hydroxide in 560 ml of water is added in turn with stirring, 300 gm (0.985 mole) of dipotassium hydroxylaminedisulfonate and 161 gm (1.0 mole) of 4-chlorobenzyl chlo­ride. The stirred mixture is heated on a steam bath for 1.75 hr. After cool­ing, the precipitate is filtered off and refluxed for 3 hr in 1000 ml of 1.5 Ν sulfuric acid. The reaction mixture is then cooled and made strongly alkaline with a 15% aqueous sodium hydroxide solution. The mixture is then extracted with ether repeatedly. The ether extracts are combined and evaporated to dryness. The solid residue (crude free base, 80 gm, i.e., 51.5% of theory, m.p. 35-38°C) is taken up in 1 liter of ether. Anhydrous hydrogen chloride is bubbled through this solution to precipitate the hy­drochloride salt. The yield is 59 gm (31%, overall), m.p. 243-244°C (dec); the free base has b.p. 100°C/1 mm Hg. In this preparation, the hydrolysis of the alkylated dipotassium hydroxyl­aminedisulfonate with only 1 liter of 1.5 Ν sulfuric acid seems somewhat skimpy. We suggest that a higher level of sulfuric acid be considered at that stage of the reaction, if the alkylation has indeed gone to completion. Once the O-alkylhydroxylamine has been prepared by this reaction, it may be N-alkylated to produce an N,Ο-dialkylhydroxylamine.
The preparation of O-phenylhydroxylamine has been a synthetic chal­lenge for some time since it is quite unstable. Using hydroxylamine-O-sulfonic acid. A small quantity of this compound has been prepared [36]. Reaction conditions probably require further study to improve the yield. Extension of the reaction to the preparation of O-alkylhydroxylamines would be of interest.

1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE Suppliers

China 45 France 1 Germany 1 India 1 United Kingdom 2 United States 10 Global 60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8836
Advantage
52
TaiZhou ZhiCheng Chemicals & Technology Co., LTD.
Tel
0523-82837785 13914525028
Fax
0523-87913272
Email
info@jszchg.com
Country
China
ProdList
249
Advantage
60
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Worldyang Chemical Co.,Ltd.
Tel
021-021-56795766
Fax
+86-21-56795266
Email
sales@worldyachem.com
Country
China
ProdList
9346
Advantage
58
Ningbo Ocean Chemical New Materials Technology Co., Ltd.
Tel
0574-86508062 18058587104
Fax
+86 (574) 87132055
Email
sales@nboceanchem.com
Country
China
ProdList
19
Advantage
60
Shanghai HuanChuan Industry Co.,Ltd.
Tel
021-61478794
Fax
021-61478794
Email
sales@hcshhai.com
Country
China
ProdList
9793
Advantage
50
Bellen Chemistry Co., Ltd.
Tel
010-60400365-8001 15910885229
Fax
010-60400361
Email
service@bellenchem.com
Country
China
ProdList
4508
Advantage
60
Zhengzhou Guancheng Laboratory equipment Sales
Tel
0371-88888888 272369594
Fax
QQ:272369594
Email
2723695949@qq.com
Country
China
ProdList
4979
Advantage
50
Birdo (Shanghai) Medical Technology Co., Ltd.
Tel
021-58099077
Fax
-
Email
sales@birdochem.com
Country
China
ProdList
185
Advantage
55
NovoChemy Ltd.
Tel
86-(0)21-31261262 373522135
Fax
86-(0)21-33250524
Email
sales@novochemy.com
Country
China
ProdList
6498
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
LinkChem Co.,Ltd.
Tel
021-021-58950110 13124863828
Fax
021-20922272
Email
sales@linkchem.cn
Country
China
ProdList
2928
Advantage
58
Wuhan FengyaoTonghui Chemical Products Co., Ltd.
Tel
027-87466105 15377573527
Email
2678564200@qq.com
Country
China
ProdList
17987
Advantage
58
Yujinpharma(Tianjin) Technology Co.,Ltd.
Tel
13370351217 kungfu1217@1
Fax
QQ1400885609
Email
kungfu1217@163.com
Country
China
ProdList
8982
Advantage
58
Guangdong wengjiang Chemical Reagent Co., Ltd.
Tel
0751-2815688 13927872512
Fax
0751-8963795
Email
3007421951@qq.com
Country
China
ProdList
10057
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418671 +8618949823763
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34563
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
571-88938639 +8617705817739
Fax
+86-571-88938652，+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52849
Advantage
58
SIMAGCHEM CORP
Tel
+86-13806087780
Email
sale@simagchem.com
Country
China
ProdList
17365
Advantage
58
CONIER CHEM AND PHARMA LIMITED
Tel
+8618523575427
Email
sales@conier.com
Country
China
ProdList
49374
Advantage
58
career henan chemical co
Tel
+86-0371-86658258 +8613203830695
Fax
0086-371-86658258
Email
factory@coreychem.com
Country
China
ProdList
29810
Advantage
58
Birdo (Shanghai) Medical Technology Co., Ltd.
Tel
021-58099077-8041 18601625411
Email
sales@birdotech.com
Country
China
ProdList
9322
Advantage
58
Taizhou Nanfeng Pharmaceutical Research Institute
Tel
18616377689
Email
nanfengdrug@163.com
Country
China
ProdList
20010
Advantage
58
Changzhou Kechem Bio-Scientific Co., LTD.
Tel
0519-68985668 13685222090
Fax
qq735434464
Email
sales@kechem.cn
Country
China
ProdList
26028
Advantage
58
Shanghai Ruipu Medical Technology Co., Ltd
Tel
15895968936
Fax
qq 1018762393
Email
1018762393@qq.com
Country
China
ProdList
10000
Advantage
58
Mainchem Co., Ltd.
Tel
--
Fax
--
Email
sarah@mainchem.com
Country
China
ProdList
6567
Advantage
58
Shanghai Troedsson Technology Co., LTD
Tel
18117455885
Email
qihongchem@163.com
Country
China
ProdList
9323
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
39995
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 13681763483
Email
product02@bidepharm.com
Country
China
ProdList
62075
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39653
Advantage
58
Jiaxing Zhejia Biotechnology Co., LTD
Tel
0573-85609002
Email
zhejia01@163.com
Country
China
ProdList
8875
Advantage
58
Zhengzhou Hong Sheng Pharmaceutical Technology Co. Ltd.
Tel
0371-55695890 15637198702
Email
1677336983@qq.com
Country
China
ProdList
13191
Advantage
58
Wuhan Fengyao Tonghui Chemical Products Co. LTD
Tel
027-87466205 15377579727
Email
1228964013@qq.com
Country
China
ProdList
8558
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
Shanghai Huasige Pharmaceutical Technology Co., LTD
Tel
13611612777 13611612777
Email
3627377363@qq.com
Country
China
ProdList
2460
Advantage
58
https://hanhongsci.com/
Tel
021-54306202 18917919676
Email
info@hanhongsci.com
Country
China
ProdList
29979
Advantage
58
SHANGHAI KEAN TECHNOLOGY CO., LTD.
Tel
+8613817748580
Fax
021-50175322
Email
cooperation@kean-chem.com
Country
China
ProdList
40066
Advantage
58
Henan Fengda Chemical Co., Ltd
Tel
+86-371-86557731 +86-13613820652
Fax
86-0371-86557731
Email
info@fdachem.com
Country
China
ProdList
20282
Advantage
58
GIHI CHEMICALS CO.,LIMITED
Tel
+8618058761490
Email
info@gihichemicals.com
Country
China
ProdList
49977
Advantage
58
PT CHEM GROUP LIMITED
Tel
+86-85511178; +86-85511178;
Email
peter68@ptchemgroup.com
Country
China
ProdList
35425
Advantage
58
Suchem Pharma Co., Ltd.
Tel
--
Fax
--
Country
China
ProdList
79
Advantage
50
Debye Scientific Corporation
Tel
--
Fax
--
Country
China
ProdList
6891
Advantage
50
Beijing ALFCHEM Science Co.,Ltd.
Tel
--
Fax
--
Country
China
ProdList
6456
Advantage
30

38936-60-6, 1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDERelated Search:

HYDROXYLAMINE Hydroxylamine hydrochloride 1-[(AMMONIOOXY)METHYL]-3-CHLOROBENZENE CHLORIDE 1-[(AMMONIOOXY)METHYL]-2-CHLOROBENZENE CHLORIDE N-[(4-CHLOROBENZOYL)OXY]-2-(4,5-DICHLORO-1H-IMIDAZOL-1-YL)ACETAMIDE 6-[(4-METHYLPHENYL)SULFANYL]IMIDAZO[2,1-B][1,3]THIAZOLE-5-CARBALDEHYDE O-(3,4-DICHLOROBENZYL)OXIME METHYL 2-([5-(([(2,4-DICHLOROBENZYL)OXY]IMINO)METHYL)IMIDAZO[2,1-B][1,3]THIAZOL-6-YL]SULFANYL)BENZENECARBOXYLATE 6-[(4-CHLOROBENZYL)SULFANYL]IMIDAZO[2,1-B][1,3]THIAZOLE-5-CARBALDEHYDE O-(2,4-DICHLOROBENZYL)OXIME 3-NITRO-4-(PHENYLSULFANYL)BENZENECARBALDEHYDE O-(3,4-DICHLOROBENZYL)OXIME 3-NITRO-4-(PHENYLSULFANYL)BENZENECARBALDEHYDE O-(2,4-DICHLOROBENZYL)OXIME 4-[(4-CHLOROPHENYL)SULFANYL]-3-NITROBENZENECARBALDEHYDE O-(3,4-DICHLOROBENZYL)OXIME 4-[(4-CHLOROPHENYL)SULFANYL]-3-NITROBENZENECARBALDEHYDE O-(2,4-DICHLOROBENZYL)OXIME O2-(4-CHLOROBENZOYL)-3-CHLOROPYRAZINE-2-CARBOHYDROXIMAMIDE 6-CHLOROIMIDAZO[2,1-B][1,3]THIAZOLE-5-CARBALDEHYDE O-(3,4-DICHLOROBENZYL)OXIME 2-(2-CHLOROETHYL)-4-OXO-3,4-DIHYDRO-2H-1,3-BENZOXAZIN-3-YL 4-CHLOROBENZOATE 3-NITRO-4-([3-(TRIFLUOROMETHYL)PHENYL]SULFANYL)BENZENECARBALDEHYDE O-(3,4-DICHLOROBENZYL)OXIME 6-(BENZYLSULFANYL)IMIDAZO[2,1-B][1,3]THIAZOLE-5-CARBALDEHYDE O-(3,4-DICHLOROBENZYL)OXIME 6-(PHENYLSULFANYL)IMIDAZO[2,1-B][1,3]THIAZOLE-5-CARBALDEHYDE O-(2,4-DICHLOROBENZYL)OXIME

  • 1-[(aminooxy)methyl]-4-chlorobenzene hydrochloride (1:1)
  • o-(p-chlorobenzyl)-hydroxylaminhydrochloride
  • O-(4-CHLOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE
  • 1-[(AMINOOXY)METHYL]-4-CHLOROBENZENE HYDROCHLORIDE
  • 1-[(AMMONIOOXY)METHYL]-4-CHLOROBENZENE CHLORIDE
  • O-(4-chlorobenzyl) hydroxylaMine
  • 4-Chlorobenzyloxyamine hydrochloride
  • O-(4-Chlorobenzyl)hydroxylamine hydrochloride 4-Chlorobenzyloxyamine hydrochloride
  • O-[(4-chlorophenyl)methyl]Hydroxylamine hydrochloride
  • Hydroxylamine, O-[(4-chlorophenyl)methyl]-, hydrochloride (1:1)
  • O-(4-CHLOROBENZYL)HYDROXYLAMINE HCL
  • O-(p-Chlorobenzyl)hydroxylamine hydrochloride
  • 38936-60-6