1-PYRENEMETHANOL
- Product Name
- 1-PYRENEMETHANOL
- CAS No.
- 24463-15-8
- Chemical Name
- 1-PYRENEMETHANOL
- Synonyms
- Ccris 6510;Pyrenemethanol;JACS-24463-15-8;1-PYRENEMETHANOL;Pyrene-1-methanol;3-Pyrenylmethanol;1-Pyrenylmethanol;pyren-1-ylMethanol;(1-Pyrenyl)methanol;RARECHEM AL BD 0667
- CBNumber
- CB9737534
- Molecular Formula
- C17H12O
- Formula Weight
- 232.28
- MOL File
- 24463-15-8.mol
1-PYRENEMETHANOL Property
- Melting point:
- 123-126 °C (lit.)
- Boiling point:
- 455.2±14.0 °C(Predicted)
- Density
- 1.321±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Solid
- pka
- 14.36±0.10(Predicted)
- color
- Pale Green to Yellow
- InChI
- InChI=1S/C17H12O/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-9,18H,10H2
- InChIKey
- NGDMLQSGYUCLDC-UHFFFAOYSA-N
- SMILES
- C1(CO)=C2C3=C4C(C=C2)=CC=CC4=CC=C3C=C1
- CAS DataBase Reference
- 24463-15-8(CAS DataBase Reference)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-24/25
- WGK Germany
- 3
- RTECS
- UR2457242
- HS Code
- 29062990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 389439
- Product name
- 1-Pyrenemethanol
- Purity
- 98%
- Packaging
- 1g
- Price
- $66.21
- Updated
- 2025/07/31
- Product number
- 389439
- Product name
- 1-Pyrenemethanol
- Purity
- 98%
- Packaging
- 10g
- Price
- $283.54
- Updated
- 2025/07/31
- Product number
- P1221
- Product name
- 1-Pyrenemethanol
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $44
- Updated
- 2025/07/31
- Product number
- P1221
- Product name
- 1-Pyrenemethanol
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $123
- Updated
- 2025/07/31
- Product number
- P989440
- Product name
- 1-Pyrenemethanol
- Packaging
- 2g
- Price
- $85
- Updated
- 2021/12/16
1-PYRENEMETHANOL Chemical Properties,Usage,Production
Chemical Properties
Yellow Solid
Uses
1-Pyrenemethanol (cas# 24463-15-8) is a compound useful in organic synthesis.
Uses
1-Pyrenemethanol can be used:
- For the synthesis of pincer-like benzene-bridged fluorescent selective sensor for adenosine-5′-triphosphate (ATP) detection.
- As a starting material for the synthesis of pyrene-end poly(glycidyl methacrylate) polymer.
- As an initiator for the synthesis of pyrene core star polymers.
- For the synthesis of 1-pyrenecarboxaldehyde, an important intermediate in pharmaceutical and agrochemical fields.
Synthesis
3029-19-4
24463-15-8
General procedure for the synthesis of 1-pyrenemethanol from 1-pyrenecarboxaldehyde: 1-pyrenecarboxaldehyde (1 g, 4.3 mmol) and dry tetrahydrofuran (20 mL) were placed in a round bottom flask. Sodium borohydride (165 mg, 4.3 mmol) was added in small portions and a small amount of methanol was added to promote dissolution (cumulative volume of methanol added was 10 mL) to obtain an orange solution. Upon completion of the reaction, the reaction was quenched with a 2% hydrochloric acid solution. Subsequently, the solvent was removed by distillation under reduced pressure. The resulting white powder was dissolved in dichloromethane, the organic phase was washed with water and dried with magnesium sulfate. The solvent was again removed by distillation under reduced pressure. Finally, the product was purified by silica gel column chromatography in 88% yield using dichloromethane as eluent. The structure of the product was confirmed by the following characterization: 1H NMR (300 MHz, CDCl3, 300K): δ (ppm) = 1.87 (s, 1H); 5.39 (s, 2H); 7.9-8.4 (m, 9H). 13C NMR {1H} (75 MHz, CDCl3, 300K): δ (ppm) = 64.03; 123.15 ; 124.87; 124.93; 125.13; 125.42; 125.45; 126.14; 126.19; 127.54; 127.63; 128.07; 128.97; 130.95; 131.42; 131.44; 133.94. ESI-MS: m/z = 254.97 [M + Na]+ , 214.99 [M-OH]+ (calculated values C17H12O: 232.09 (exact mass); 232.28 (molecular weight)).UV-Vis (DCM): λmax (nm) = 314; 327; 344.
References
[1] Molecules, 2011, vol. 16, # 8, p. 6950 - 6968
[2] Journal of the American Chemical Society,
[3] Journal of the American Chemical Society, 2008, vol. 130, p. 12846 - 12847
[4] Analytical Chemistry, 2018, vol. 90, # 2, p. 1402 - 1407
[5] Journal of Physical Chemistry A, 2003, vol. 107, # 40, p. 8363 - 8370
1-PYRENEMETHANOL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-PYRENEMETHANOL manufacturers
- Product
- 1-Pyrenemethanol 24463-15-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-22
- Product
- 1-Pyrenemethanol 24463-15-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 1-PYRENEMETHANOL 24463-15-8
- Price
- US $6.68/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2020-01-08