3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID
- Product Name
- 3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID
- CAS No.
- 34970-18-8
- Chemical Name
- 3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID
- Synonyms
- 3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID;3,3-dimethylcyclobutane-1-carboxylic acid;Cyclobutanecarboxylic acid, 3,3-dimethyl-
- CBNumber
- CB9805787
- Molecular Formula
- C7H12O2
- Formula Weight
- 128.17
- MOL File
- 34970-18-8.mol
3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID Property
- Boiling point:
- 206℃
- Density
- 1.053
- Flash point:
- 96℃
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.82±0.40(Predicted)
- form
- liquid
- color
- Colourless
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- D460090
- Product name
- 3,3-DimethylcyclobutanecarboxylicAcid
- Packaging
- 500mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- 4278AB
- Product name
- 3,3-Dimethylcyclobutanecarboxylicacid
- Packaging
- 1g
- Price
- $216
- Updated
- 2021/12/16
- Product number
- FD164844
- Product name
- 3,3-Dimethylcyclobutane-1-carboxylic acid
- Packaging
- 500mg
- Price
- $260
- Updated
- 2021/12/16
- Product number
- FD164844
- Product name
- 3,3-Dimethylcyclobutane-1-carboxylic acid
- Packaging
- 100mg
- Price
- $83
- Updated
- 2021/12/16
- Product number
- 2221-1-27
- Product name
- 3,3-Dimethylcyclobutanecarboxylic acid
- Purity
- 97%
- Packaging
- 250mg
- Price
- $93
- Updated
- 2021/12/16
3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID Chemical Properties,Usage,Production
Synthesis
231303-93-8
34970-18-8
The general procedure for the synthesis of 3,3-dimethylcyclobutanecarboxylic acid from the compound (CAS:231303-93-8) was as follows: intermediate 285C (250 mg, 1.452 mmol) was dissolved in pyridine (5 mL) and the reaction was stirred for 16 h at 120 °C. After completion of the reaction, the reaction mixture was cooled to room temperature and the reaction was quenched with 1.5 N HCl aqueous solution. Subsequently, extraction was carried out with ether (2 x 50 mL) at 0 °C. The organic layers were combined, washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to afford intermediate 285D as a viscous liquid (170 mg, 91% yield).1H NMR (400 MHz, DMSO-d6) δ ppm: 2.90-3.02 (m, 1H), 1.84-1.95 (m, 4H), 1.07-1.14 (m, 3H) , 0.99-1.07 (m, 3H).
References
[1] Patent: US9273058, 2016, B2. Location in patent: Page/Page column 329; 330; 331
[2] Tetrahedron, 1999, vol. 55, # 19, p. 6119 - 6128
[3] Tetrahedron Letters, 1990, vol. 31, # 21, p. 2975 - 2978
[4] Patent: WO2015/129926, 2015, A1. Location in patent: Page/Page column 101
3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID manufacturers
- Product
- 3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID 34970-18-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-08-09
- Product
- 3,3-DIMETHYLCYCLOBUTANECARBOXYLIC ACID 34970-18-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-02