methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate

Product Name: methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate
CAS No.: 255050-65-8
Chemical Name: methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate
Synonyms: methyl 6-(((trifluoromethyl)sulfonyl)oxy)-1-naphthoate;6-[[(trifluoromethyl)sulfonyl]oxy]-1-Naphthalenecarboxylic acid methylester;1-Naphthalenecarboxylic acid, 6-[[(trifluoromethyl)sulfonyl]oxy]-, methyl ester
CBNumber: CB98098086
Molecular Formula: C13H9F3O5S
Formula Weight: 334.27
MOL File: 255050-65-8.mol

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methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate Chemical Properties,Usage,Production

Synthesis

The synthesis of methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate is as follows:
Diisopropylethyiamine (2.35 mL, 13,5 mmol) and irifluoromethanesuifonic anhydride (0,95 mL, 5.6 mmol) were added sequentially to a solution of methyl 6-hydroxy- l- naphthoate ( 10 mg, 4.5 mmol) in CH2C12 (60 mL) at - 78 °C. After 1 h at - 78 °C, the reaction mixture was poured into saturated aqueous NH4C1 (30 mL). The resulting mixture was extracted with CH2CI2 (3x50 mL). The combined organic phase was washed with brine (50 mL) then dried ( a2S0 ), filtered and concentrated in vacuo. The resulting residue was purified on 80 g silica gel (100% hexanes - 100% EtOAc, gradient) to afford 1 ,45 g (96%) of methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate.

methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoate Preparation Products And Raw materials

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255050-65-8, methyl 6-(trifluoromethylsulfonyloxy)-1-naphthoateRelated Search:

1-Naphthalenecarboxylic acid, 6-[[(trifluoromethyl)sulfonyl]oxy]-, methyl ester

methyl 6-(((trifluoromethyl)sulfonyl)oxy)-1-naphthoate

6-[[(trifluoromethyl)sulfonyl]oxy]-1-Naphthalenecarboxylic acid methylester

255050-65-8