ChemicalBook > CAS DataBase List > 2,3,3,4-biphenyl tetracarboxylic dianhydride

2,3,3,4-biphenyl tetracarboxylic dianhydride

Product Name
2,3,3,4-biphenyl tetracarboxylic dianhydride
CAS No.
36978-41-3
Chemical Name
2,3,3,4-biphenyl tetracarboxylic dianhydride
Synonyms
A-BPDA;α-BPDA;DF2DK;JACS-36978-41-3;2,3,3',4'-BIPHENYL;3,3',4',4'-BIPHENYL;1,1'-Biphenyl-2,3,3',4'-;3,4'-Biphthalic anhydride;4,5'-Bi(1,3-isobenzofurandione);4,5'-Bi[isobenzofuran-1,3-dione]
CBNumber
CB9839416
Molecular Formula
C16H6O6
Formula Weight
294.22
MOL File
36978-41-3.mol
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2,3,3,4-biphenyl tetracarboxylic dianhydride Property

Melting point:
199 °C
Boiling point:
609.3±48.0 °C(Predicted)
Density 
1.625±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
color 
White to Almost white
InChI
InChI=1S/C16H6O6/c17-13-9-5-4-7(6-11(9)15(19)21-13)8-2-1-3-10-12(8)16(20)22-14(10)18/h1-6H
InChIKey
FYYYKXFEKMGYLZ-UHFFFAOYSA-N
SMILES
C1(=O)C2=C(C(C3C=CC4C(=O)OC(=O)C=4C=3)=CC=C2)C(=O)O1
CAS DataBase Reference
36978-41-3(CAS DataBase Reference)
EPA Substance Registry System
[4,5'-Biisobenzofuran]-1,1',3,3'-tetrone (36978-41-3)
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Safety

HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4629
Product name
3,4'-Biphthalic Anhydride
Packaging
5G
Price
$63
Updated
2024/03/01
Biosynth Carbosynth
Product number
FB150779
Product name
2,3,3',4'-Biphenyl tetracarboxylicdianhydride
Packaging
100mg
Price
$73
Updated
2021/12/16
Apolloscientific
Product number
OR41022
Product name
3,4'-Biphthalic Anhydride
Packaging
1g
Price
$15
Updated
2021/12/16
SynQuest Laboratories
Product number
2H26-1-28
Product name
3,4'-Biphthalic Anhydride
Packaging
1g
Price
$16
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB150779
Product name
2,3,3',4'-Biphenyl tetracarboxylicdianhydride
Packaging
1g
Price
$440
Updated
2021/12/16
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2,3,3,4-biphenyl tetracarboxylic dianhydride Chemical Properties,Usage,Production

Description

2,3,3,4-biphenyl tetracarboxylic dianhydride, also known as a-BPDA, is a high-performance polymer with excellent heat resistance, solvent resistance, radiation resistance, and impressive mechanical and dielectric properties. It holds great potential for applications across numerous industries and material fields.

Chemical Properties

White to Almost white powder to crystal.

Uses

2,3,3',4'-Biphenyltetracarboxylic dianhydride be used for the preparation of a polyimide material.

Preparation

The preparation of 2,3,3',4'-biphenyl tetracarboxylic dianhydride is as follows:In a 1000 ml three-necked flask, 18.3 g (0.1 mol) of 4-chlorophthalic anhydride and 18.3 g (0.1 mol) were added 3-chlorophthalic anhydride, 300 g of anisole as solvent, 0.13 g (0.001 mol) of nickel chloride as a catalyst, 0.198 g (0.001 mol) of C-1 as a catalyst ligand, and 0.03 g (0.0003 mol) of sodium bromide as a catalyst Auxiliary, 13 g (0.2 mol) of zinc powder was used as a reducing agent, and the reaction was stirred at 30 ° C for 8 hours under a nitrogen atmosphere. The reaction solution was filtered to remove insoluble solids in the reaction liquid. 300 g of methanol was added to the filtration mother liquor, and the product was precipitated, filtered, and dried to obtain 25.8 g of the product 2,3,3',4'-biphenyltetracarboxylic dianhydride, yield 87.7%. 

2,3,3,4-biphenyl tetracarboxylic dianhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2,3,3,4-biphenyl tetracarboxylic dianhydride manufacturers

Henan Fengda Chemical Co., Ltd
Product
2,3,3',4'-Biphenyl tetracarboxylic dianhydride 36978-41-3
Price
US $122.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-11
Shanghai Daken Advanced Materials Co.,Ltd
Product
2,3,3',4'-BiphenyLtetracarboxylic 36978-41-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99.00%
Supply Ability
1500KG/month
Release date
2021-11-01
Hebei Mojin Biotechnology Co., Ltd
Product
2,3,3',4'-BIPHENYL TETRACARBOXYLIC DIANHYDRIDE 36978-41-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16

36978-41-3, 2,3,3,4-biphenyl tetracarboxylic dianhydrideRelated Search:


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