Methallyl alcohol Property

Melting point:

-50 °C

Boiling point:

113-115 °C(lit.)

Density 

0.857 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.426(lit.)

Flash point:

92 °F

storage temp. 

Flammables area

solubility 

Chloroform (Slightly), Methanol (Slightly)

form 

clear liquid

pka

14.49±0.10(Predicted)

Specific Gravity

0.8515

color 

Colorless to Almost colorless

Water Solubility 

11 g/100 mL

BRN 

969226

Stability:

Light Sensitive

CAS DataBase Reference

513-42-8(CAS DataBase Reference)

NIST Chemistry Reference

2-Propen-1-ol, 2-methyl-(513-42-8)

EPA Substance Registry System

Methallyl alcohol (513-42-8)

Safety

Hazard Codes 

Xi

Risk Statements 

10-36/37/38

Safety Statements 

26-36-37/39-16

RIDADR 

UN 2614 3/PG 3

WGK Germany 

3

RTECS 

UD5250000

TSCA 

Yes

HazardClass 

3.2

PackingGroup 

III

HS Code 

29052900

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Methallyl alcohol Chemical Properties,Usage,Production

Description

Methallyl alcohol is a colorless liquid with a pungent odor. Molecular weight= 72.12;Boiling point=114℃; Flash point=33℃. Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 3, Reactivity 0. Slightly soluble in water.

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

2-Methyl-2-propen-1-ol (MePro) attaches to hemicellulose acetylated galactoglucomannan (AcGGM) backbone providing it with pendant sites that allow subsequent cross-linking and hydrogel formation.

Production Methods

Methallyl alcohol is prepared by hydrolysis of methallyl chloride in a 10 wt% aqueous sodium hydroxide solution. Pure methallyl alcohol can be obtained by methanolysis of methallyl acetate in the presence of catalytic amounts of bases. Methallyl alcohol is used in the preparation of polymerizable esters.

General Description

A colorless liquid with a sharp pungent odor. Soluble in water and floats on water. Moderately toxic by ingestion and is an irritant to eyes and skin. Used in the chemical process industry.

Air & Water Reactions

Highly flammable and soluble in water.

Reactivity Profile

Methallyl alcohol may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.

Health Hazard

Exposure can cause irritation of eyes, nose and throat.

Potential Exposure

Used as an intermediate in organic synthesis

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

storage

Color Code—Red: Flammability Hazard: Store in a flammable liquid storage area or approved cabinet away from ignition sources and corrosive and reactive materials. Prior to working with this chemical you should be trained on its proper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers and other incompatible materials. Metal containers involving the transfer of this chemical should be grounded and bonded. Drums must be equipped with self-closing valves. Sources of ignition, such as smoking and open flames, are prohibited where this chemical is used, handled, or stored in a manner that could create a potential fire or explosion hazard.

Shipping

This compound requires a shipping label of “FLAMMABLE LIQUID.” It falls in Hazard Class 3 and Packing Group II.

Incompatibilities

Forms explosive mixture with air. Incompatible with strong acids, caustics, aliphatic amines, isocyanates, DMSO, oxidizers.