4-Chloro-2-methylaniline

ChemicalBook > CAS DataBase List > 4-Chloro-2-methylaniline

4-Chloro-2-methylaniline

Product Name: 4-Chloro-2-methylaniline
CAS No.: 95-69-2
Chemical Name: 4-Chloro-2-methylaniline
Synonyms: 4-CHLORO-O-TOLUIDINE;P-CHLORO-O-TOLUIDINE;FAST RED TR BASE;Ipsilon;devalredk;fastredtr;devalredtr;redbasentr;Deval Red K;Fast Red TR
CBNumber: CB9854705
Molecular Formula: C7H8ClN
Formula Weight: 141.6
MOL File: 95-69-2.mol

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4-Chloro-2-methylaniline Property

Melting point:: 24-27 °C (lit.)
Boiling point:: 241 °C (lit.)
Density: 1.19 g/mL at 25 °C (lit.)
refractive index: n20/D 1.583(lit.)
Flash point:: 211 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
Water Solubility: Practically insoluble in water
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: pK1:3.385(+1) (25°C)
color: White or colorless to Brown
BRN: 878505
Stability:: Air Sensitive
CAS DataBase Reference: 95-69-2(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 4-chloro-2-methyl-(95-69-2)
IARC: 2A (Vol. 77, 99) 2010
EPA Substance Registry System: 4-Chloro-2-methylaniline (95-69-2)

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Safety

Hazard Codes: T,N
Risk Statements: 45-23/24/25-50/53-68
Safety Statements: 53-45-60-61
RIDADR: UN 2239 6.1/PG 3
WGK Germany: 3
RTECS: XU5000000
F: 8-10
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29214300
Hazardous Substances Data: 95-69-2(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H341Suspected of causing genetic defects

H350May cause cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 590711
Product name: 4-Chloro-2-methylaniline
Purity: 98%
Packaging: 10g
Price: $69.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 46282
Product name: 4-Chloro-2-methylaniline
Purity: analytical standard
Packaging: 250mg
Price: $53.6
Updated: 2022/05/15

TCI Chemical

Product number: A0704
Product name: 4-Chloro-2-methylaniline
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $28
Updated: 2024/03/01

TCI Chemical

Product number: A0704
Product name: 4-Chloro-2-methylaniline
Purity: >98.0%(GC)(T)
Packaging: 100g
Price: $63
Updated: 2024/03/01

TCI Chemical

Product number: A0704
Product name: 4-Chloro-2-methylaniline
Purity: >98.0%(GC)(T)
Packaging: 500g
Price: $186
Updated: 2024/03/01

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4-Chloro-2-methylaniline Chemical Properties,Usage,Production

Chemical Properties

clear brown liquid

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Uses

Intermediate.

Uses

4-Chloro-2-methylaniline may be used in the synthesis of the following:

2,8-dichloro-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f]-diazocine via reaction with paraformaldehyde in toluene
N-allylated derivative via palladium-catalyzed selective monoallylation with allyl alcohol
N-(4-chloro-2-methylphenyl)benzamide via reaction with benzoyl chloride

Definition

ChEBI: 4-Chloro-ortho-toluidine is a member of monochlorobenzenes.

General Description

Gray to white solid with a weak fishy odor. Sinks in water. Freezing point is 77°F.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

4-Chloro-2-methylaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . A halogenated amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion and inhalation. Probable carcinogen.

Health Hazard

Inhalation, ingestion, or skin contact causes bluish tint in fingernails, lips, and ears. Headache, drowsiness, and nausea also occur. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen and hydrochloric acid fumes may form.

Safety Profile

Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloro toluidme entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Carcinogenicity

p-Chloro-o-toluidine and its hydrochloride salt are reasonably anticipated to be human carcinogens based on limited evidence of carcinogenicity from studies in humans and evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

4-Chloro-2-methylaniline Preparation Products And Raw materials

Raw materials

Glycine o-Toluidine Benzoyl chloride

Preparation Products

4-CHLORO-2-METHYLBENZOIC ACID CHLOROMETHIURON 4-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE

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View Lastest Price from 4-Chloro-2-methylaniline manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4-Chloro-2-methylaniline 95-69-2
Price: US $30.00-10.00/kg
Min. Order: 10kg
Purity: 99%
Supply Ability: 100000kg
Release date: 2024-08-22

Henan Fengda Chemical Co., Ltd

Product: 4-Chloro-2-Methylaniline 95-69-2
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-31

Honest Joy Holdings Limited

Product: 4-Chloro-2-methylaniline 95-69-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.6%
Supply Ability: 100 tons
Release date: 2022-02-18

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fastredbasetr

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kambamineredtr

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mitsuiredtrbase

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Red Base Irga IX

Red Base NTR

redbasecibaix

redbaseirgaix

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