ChemicalBook > CAS DataBase List > 5,6-dihydro-2H-pyran-3-carbaldehyde

5,6-dihydro-2H-pyran-3-carbaldehyde

Product Name
5,6-dihydro-2H-pyran-3-carbaldehyde
CAS No.
13417-49-7
Chemical Name
5,6-dihydro-2H-pyran-3-carbaldehyde
Synonyms
EINECS 236-515-4;5,6-Dihydro-2H-pyran-3-carbaldehyde;3,6-dihydro-2H-pyran-5-carbaldehyde;5, 6-dihydro-2-H pyran-3-formaldehyde;2H-Pyran-3-carboxaldehyde, 5,6-dihydro-
CBNumber
CB9890956
Molecular Formula
C6H8O2
Formula Weight
112.13
MOL File
13417-49-7.mol
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5,6-dihydro-2H-pyran-3-carbaldehyde Property

Boiling point:
49.2 °C
Density 
1.114 g/cm3
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
Appearance
Colorless to light yellow Liquid
InChI
InChI=1S/C6H8O2/c7-4-6-2-1-3-8-5-6/h2,4H,1,3,5H2
InChIKey
RKXCKEHBMLDWET-UHFFFAOYSA-N
SMILES
C1OCCC=C1C=O
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Safety

HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
D453330
Product name
5,6-Dihydro-2H-pyran-3-carboxaldehyde
Packaging
1g
Price
$165
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD142326
Product name
5,6-Dihydro-2H-pyran-3-carbaldehyde
Packaging
250mg
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD142326
Product name
5,6-Dihydro-2H-pyran-3-carbaldehyde
Packaging
500mg
Price
$115
Updated
2021/12/16
AK Scientific
Product number
Z4103
Product name
5,6-Dihydro-2H-pyran-3-carbaldehyde
Packaging
250mg
Price
$146
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD142326
Product name
5,6-Dihydro-2H-pyran-3-carbaldehyde
Packaging
1g
Price
$200
Updated
2021/12/16
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5,6-dihydro-2H-pyran-3-carbaldehyde Chemical Properties,Usage,Production

Uses

5,6-Dihydro-2H-pyran-3-carboxaldehyde is a useful synthetic intermediate and a derivative of acrolein (A191200); a compound well-known for its use in the synthesis of acrylic acid.

Synthesis

107-02-8

13417-49-7

Acrolein [stabilized] (40 g, 713 mmol) was dissolved in a solvent mixture of dichloromethane (105 mL) and deionized water (2.3 mL) at room temperature and stirred to form a homogeneous mixture. Phosphoric acid (12.7 mL) was slowly added dropwise to the above mixture. The reaction system was heated to reflux and the reaction was continued overnight. Upon completion of the reaction, the reaction mixture was purified by reduced pressure distillation (110-150 °C, 20 mmHg) to afford the target product 5,6-dihydro-2-H pyran-3-carbaldehyde (12.6 g, 15.7% yield). Mass spectrometry result (m/z): [M + H]+ 113.1.

References

[1] Monatshefte fuer Chemie, 1990, vol. 121, # 11, p. 963 - 970
[2] New Journal of Chemistry, 2008, vol. 32, # 8, p. 1354 - 1358
[3] Angewandte Chemie - International Edition, 2013, vol. 52, # 23, p. 6072 - 6075
[4] Angew. Chem., 2013, vol. 125, # 23, p. 6188 - 6191
[5] Patent: WO2016/85939, 2016, A2. Location in patent: Paragraph 00259

5,6-dihydro-2H-pyran-3-carbaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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5,6-dihydro-2H-pyran-3-carbaldehyde Suppliers

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View Lastest Price from 5,6-dihydro-2H-pyran-3-carbaldehyde manufacturers

Career Henan Chemical Co
Product
5,6-dihydro-2H-pyran-3-carbaldehyde 13417-49-7
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000kg
Release date
2020-01-13

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  • EINECS 236-515-4
  • 5,6-Dihydro-2H-pyran-3-carbaldehyde
  • 2H-Pyran-3-carboxaldehyde, 5,6-dihydro-
  • 5, 6-dihydro-2-H pyran-3-formaldehyde
  • 3,6-dihydro-2H-pyran-5-carbaldehyde
  • 13417-49-7