Basic information Safety Supplier Related

1-(BROMOACETYL)PYRENE

Basic information Safety Supplier Related

1-(BROMOACETYL)PYRENE Basic information

Product Name:
1-(BROMOACETYL)PYRENE
Synonyms:
  • 1-(BROMOACETYL)PYRENE
  • 2-bromo-1-(1-pyrenyl)Ethanone
  • 2-bromo-1-(pyren-3-yl)ethanone
  • 2-broMo-1-(pyren-1-yl)ethanone
  • 1-(Bromoacetyl)pyrene 97%
  • Ethanone, 2-bromo-1-(1-pyrenyl)-
  • 2-bromo-1-(pyren-1-yl)ethan-1-one
CAS:
80480-15-5
MF:
C18H11BrO
MW:
323.18
Product Categories:
  • C15 to C38
  • Carbonyl Compounds
  • Ketones
Mol File:
80480-15-5.mol
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1-(BROMOACETYL)PYRENE Chemical Properties

Melting point:
129-131 °C (lit.)
Boiling point:
476.7±18.0 °C(Predicted)
Density 
1.563±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
Solid
color 
Yellow to Dark Yellow
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
22-26-36/37/39-45
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
HS Code 
29147000

MSDS

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1-(BROMOACETYL)PYRENE Usage And Synthesis

Chemical Properties

Yellow solid

Uses

1-(Bromoacetyl)pyrene is suitable for use in the following studies:

  • As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
  • As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
  • As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.
It may also be used in the following studies:
  • As a photoremovable protecting group for carboxylic acids and amino acids.
  • As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
  • As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
  • As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.

General Description

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

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