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Bis(benzonitrile)dibromopalladium(II)

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Bis(benzonitrile)dibromopalladium(II) Basic information

Product Name:
Bis(benzonitrile)dibromopalladium(II)
Synonyms:
  • Bis(benzonitrile)dibromopalladium(II)
  • Bis(benzonitrile)palladium(II) bromide
  • Bis(benzonitrile)palladium(II) bromide 95%
CAS:
15003-43-7
MF:
C14H12Br2N2Pd
MW:
474.49
Mol File:
15003-43-7.mol
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Bis(benzonitrile)dibromopalladium(II) Chemical Properties

Melting point:
95-102°C
solubility 
sol benzene, methanol.
form 
solid
color 
dark brown crystals.
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Safety Information

WGK Germany 
3
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Bis(benzonitrile)dibromopalladium(II) Usage And Synthesis

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Synthesis

Bis(benzonitrile)dibromopalladium(II) is prepared in 90% yield by reacting PdBr2 in PhCN with prolonged heating at 100 °C. The reaction mixture is filtered while hot and the filtrate cooled to give a brown precipitate. Additional product is obtained by precipitation with cyclohexane.

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