9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Basic information
- Product Name:
- 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
- Synonyms:
-
- 9-Borabicyclo[3.3.1]nonane,9-methoxy-
- 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
- 9-Methoxy-9-borabicycL
- B-METHOXY-9-BBN
- B-METHOXY-9-BBN, 1.0M SOLUTION IN HEXANE S
- b-methoxy-9-bbn solution
- 8-Methoxy-9-borabicyclo[3,3,1]nonane
- 9- methoxy-9-borabicyclo[3.3.1]nonane 1.0M in hexanes
- CAS:
- 38050-71-4
- MF:
- C9H17BO
- MW:
- 152.04
- EINECS:
- 253-758-1
- Mol File:
- 38050-71-4.mol
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9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Chemical Properties
- Boiling point:
- 57-58 °C(Press: 7 Torr)
- Density
- 0.716 g/mL at 25 °C
- Flash point:
- −9 °F
- InChI
- InChI=1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3
- InChIKey
- UNGDGQYONLTNJZ-UHFFFAOYSA-N
- SMILES
- C12B(OC)C(CCC1)CCC2
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Safety Information
- Hazard Codes
- F,Xn,N
- Risk Statements
- 11-20/21/22-67-65-62-51/53-48/20-38
- Safety Statements
- 16-23-36/37/39-45-62-61-36/37
- RIDADR
- UN 1993 3/PG 2
- WGK Germany
- 3
MSDS
- Language:English Provider:SigmaAldrich
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9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Usage And Synthesis
Uses
Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives. Catalyst for preparation of linear allenes from other allenes 2 Reactant for: Stereoconvergent Suzuki cross-coupling reactions 3 B-alkyl Suzuki-Miyaura cross-coupling reactions 4 Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma 5 Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement.
Uses
9-Methoxy-9-borabicyclo[3.3.1]nonane is a coupling reagent used in reactions like the synthesis of (-)-brevenal a polycyclic ether.
Uses
- Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives
- Catalyst for preparation of linear allenes from other allenes
Reactant for:
- Stereoconvergent Suzuki cross-coupling reactions
- B-alkyl Suzuki-Miyaura cross-coupling reactions
- Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma
- Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement
9-METHOXY-9-BORABICYCLO[3.3.1]NONANESupplier
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