Basic information Safety Supplier Related

9-METHOXY-9-BORABICYCLO[3.3.1]NONANE

Basic information Safety Supplier Related

9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Basic information

Product Name:
9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
Synonyms:
  • 9-Borabicyclo[3.3.1]nonane,9-methoxy-
  • 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
  • 9-Methoxy-9-borabicycL
  • B-METHOXY-9-BBN
  • B-METHOXY-9-BBN, 1.0M SOLUTION IN HEXANE S
  • b-methoxy-9-bbn solution
  • 8-Methoxy-9-borabicyclo[3,3,1]nonane
  • 9- methoxy-9-borabicyclo[3.3.1]nonane 1.0M in hexanes
CAS:
38050-71-4
MF:
C9H17BO
MW:
152.04
EINECS:
253-758-1
Mol File:
38050-71-4.mol
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9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Chemical Properties

Boiling point:
57-58 °C(Press: 7 Torr)
Density 
0.716 g/mL at 25 °C
Flash point:
−9 °F
InChI
InChI=1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3
InChIKey
UNGDGQYONLTNJZ-UHFFFAOYSA-N
SMILES
C12B(OC)C(CCC1)CCC2
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Safety Information

Hazard Codes 
F,Xn,N
Risk Statements 
11-20/21/22-67-65-62-51/53-48/20-38
Safety Statements 
16-23-36/37/39-45-62-61-36/37
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3

MSDS

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9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Usage And Synthesis

Uses

Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives. Catalyst for preparation of linear allenes from other allenes 2 Reactant for: Stereoconvergent Suzuki cross-coupling reactions 3 B-alkyl Suzuki-Miyaura cross-coupling reactions 4 Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma 5 Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement.

Uses

9-Methoxy-9-borabicyclo[3.3.1]nonane is a coupling reagent used in reactions like the synthesis of (-)-brevenal a polycyclic ether.

Uses

  • Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives
  • Catalyst for preparation of linear allenes from other allenes

Reactant for:
  • Stereoconvergent Suzuki cross-coupling reactions
  • B-alkyl Suzuki-Miyaura cross-coupling reactions
  • Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma
  • Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement

9-METHOXY-9-BORABICYCLO[3.3.1]NONANESupplier

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