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NONAFLUOROHEXYLTRIMETHOXYSILANE

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NONAFLUOROHEXYLTRIMETHOXYSILANE Basic information

Product Name:
NONAFLUOROHEXYLTRIMETHOXYSILANE
Synonyms:
  • NONAFLUOROHEXYLTRIMETHOXYSILANE
  • TriMethoxy(1H,1H,2H,2H-nonafluorohexyl)silane
  • Nonafluorobutylethyltrimethoxysilane
  • Nonafluoro-1,1,2,2-tetrahydrohexyltrimethoxysilane
  • Dow Corning B 3958
  • 3,3,4,4,5,5,6,6,6-Nonafluorohexyltrimethoxysilane
  • (1,1,2,2-Tetrahydrononafluorohexyl)trimethoxysilane
  • Trimethoxy(1H,1H,2H,2H-nonafluorohexyl)silane
CAS:
85877-79-8
MF:
C9H13F9O3Si
MW:
368.27
EINECS:
248-418-4
Mol File:
85877-79-8.mol
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NONAFLUOROHEXYLTRIMETHOXYSILANE Chemical Properties

Boiling point:
68-9°C/15mmHg
Density 
1,335 g/cm3
refractive index 
1.3376
Flash point:
71°C(lit.)
storage temp. 
Storage temp. 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.335
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChI
InChI=1S/C9H13F9O3Si/c1-19-22(20-2,21-3)5-4-6(10,11)7(12,13)8(14,15)9(16,17)18/h4-5H2,1-3H3
InChIKey
IJROHELDTBDTPH-UHFFFAOYSA-N
SMILES
[Si](OC)(OC)(OC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)F
EPA Substance Registry System
((Perfluorobutyl)ethyl)trimethoxysilane (85877-79-8)
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Safety Information

TSCA 
No
HS Code 
2931.90.9010
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NONAFLUOROHEXYLTRIMETHOXYSILANE Usage And Synthesis

Uses

Non-fluorohexyltrimethoxysilane (NFTOS) is used as a weakly coordinating additive to enhance the compatibility between phosphate-based solvents and sodium metal anodes. NFTOS exhibits super-wetting properties on alkali metal anodes, effectively reducing the contact angle between the electrolyte and the sodium anode (from 49.3° to 38.6°), thereby enabling the electrolyte to better wet and penetrate the electrode surface. By improving wettability, NFTOS helps to form a more uniform and dense inorganic solid electrolyte interphase (SEI) film on the sodium anode surface, which contributes to enhancing the battery's cycling stability and safety[1].

References

[1] Song, X., Liang, X., Kim, M., & Sun, Y. (2025). Customized Solvation Structure for Stable and Safe Sodium‐Metal Batteries. Advanced Energy Materials, 81 1. https://doi.org/10.1002/aenm.202504683

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