2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE Basic information
- Product Name:
- 2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE
- Synonyms:
-
- 2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE
- tert-butyl(1,3-dithian-2-yl)diMethylsilane
- 1,3-Dithiane, 2-[(1,1-dimethylethyl)dimethylsilyl]-
- CAS:
- 95452-06-5
- MF:
- C10H22S2Si
- MW:
- 234.5
- Product Categories:
-
- Heterocyclic Compounds
- Heterocyclic Building Blocks
- Others
- S-Containing
- Mol File:
- 95452-06-5.mol
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2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE Chemical Properties
- Boiling point:
- 124 °C5 mm Hg(lit.)
- Density
- 1.01 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.531(lit.)
- Flash point:
- 221 °F
- solubility
- insoluble in H2O; soluble in organic solvents.
MSDS
- Language:English Provider:SigmaAldrich
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2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE Usage And Synthesis
Physical properties
bp 115°C/0.03mmHg, 124°C/5mmHg, d 1.010.
Uses
2-t-Butyldimethylsilyl-1,3-dithiane can be as an anion undergoes alkylation with electrophiles subsequently providing a general synthesis to acyl silanes;anion undergoes.
Preparation
prepared by alkylation of 2-lithio-1,3-dithiane with t-butyldimethylsilyl chloride (eq 1).
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANESupplier
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