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Nickel sulfide

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Nickel sulfide Basic information

Product Name:
Nickel sulfide
Synonyms:
  • nickeltritadisulphide[qr]
  • trinickeldisulfide
  • trinickeldisulphide
  • Nickel subsulfide (as Ni)(trinickel disulfide) total dust
  • Nickel sulphide roasting (fumes & dust) (as Ni) (also see metal)
  • nickel subsulphide trinickel disulphide
  • Nickel sulfide, 99.9% trace metals basis
  • Heazlewoodite
CAS:
12035-72-2
MF:
Ni3S2
MW:
240.21
EINECS:
234-829-6
Product Categories:
  • Inorganics
Mol File:
12035-72-2.mol
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Nickel sulfide Chemical Properties

Melting point:
797℃
Density 
5.8 g/mL at 25 °C(lit.)
form 
Powder
color 
Black
Water Solubility 
Soluble in water(0,00735 g/L at 20°C).
Exposure limits
ACGIH: TWA 0.1 mg/m3; TWA 0.2 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference
12035-72-2
EPA Substance Registry System
Nickel subsulfide (12035-72-2)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
49-43-51/53-68-50/53-48/23-20
Safety Statements 
53-45-61-60
RIDADR 
UN 3077 9/PG 3
WGK Germany 
2
RTECS 
QR9800000
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
28309090
Hazardous Substances Data
12035-72-2(Hazardous Substances Data)
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Nickel sulfide Usage And Synthesis

Chemical Properties

yellowish; naturally occurring nickel mineral [KIR81] [CRC10]

Uses

Nickel subsulfide is used as a catalyst in refining crude oil containing a considerable amount of sulfur.

Uses

Nickel sulfide was implanted in mice, to induce the growth of malignant fibrous histiocytomas.

Production Methods

Nickel subsulfide can be prepared by a direct reaction between nickel and sulfur at a temperature over 300C. This process makes it possible to prepare the purest preparation in the form of a brittle melt or monocrystals. The largest industrial source of nickel subsulfide is the metallurgic process of nickel matte smelting. Nickel matte consists of nickel subsulfide and some quantities of iron and copper sulfides. It is an intermediate product in nickel metallurgy regardless of the type of the processed ores.

General Description

Pale yellowish-bronze metallic-lustrous crystals or shiny gold-green (metallic) crystalline powder.

Air & Water Reactions

NICKEL SULFIDE -150 MESH 99.7% is sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

Inorganic sulfides, such as NICKEL SULFIDE -150 MESH 99.7%, are generally basic and therefore incompatible with acids. Many of these compounds are reducing agents and therefore react vigorously with oxidizing agents, including inorganic oxoacids, organic peroxides and epoxides. Simple salts of sulfides (such as sodium, potassium, and ammonium sulfide) react vigorously with acids to release hydrogen sulfide gas.

Fire Hazard

Flash point data for NICKEL SULFIDE -150 MESH 99.7% are not available. NICKEL SULFIDE -150 MESH 99.7% is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic, and teratogenic data. Poison by intraperitoneal and intratracheal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also NICKEL COhlPOUNDS and SULFIDES.

Nickel sulfideSupplier

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