Basic information Safety Supplier Related

CIS-3-IODOACRYLIC ACID ETHYL ESTER

Basic information Safety Supplier Related

CIS-3-IODOACRYLIC ACID ETHYL ESTER Basic information

Product Name:
CIS-3-IODOACRYLIC ACID ETHYL ESTER
Synonyms:
  • ethyl (Z)-3-iodoacrylate
  • ethyl (Z)-3-iodopropenoate
  • CIS-3-IODOACRYLIC ACID ETHYL ESTER
  • ETHYL CIS-3-IODOACRYLATE
  • Ethyl cis-3-Iodoacrylate (stabilized with Copper chip)
  • (Z)-ethyl 3-iodoacrylate
  • Ethyl cis-3-iodoacrylate 98%
  • Ethyl cis-3-Iodoacrylate 
CAS:
31930-36-6
MF:
C5H7IO2
MW:
226.01
Product Categories:
  • Building Blocks
  • C2 to C5
  • C2 to C5
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks
  • Carbonyl Compounds
  • Esters
Mol File:
31930-36-6.mol
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CIS-3-IODOACRYLIC ACID ETHYL ESTER Chemical Properties

Boiling point:
85 °C/20 mmHg (lit.)
Density 
1.765 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.533(lit.)
Flash point:
210 °F
storage temp. 
2-8°C
solubility 
Chloroform, Ethyl Acetate (Slightly)
form 
Oil
color 
Clear Colourless
CAS DataBase Reference
31930-36-6
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29161900

MSDS

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CIS-3-IODOACRYLIC ACID ETHYL ESTER Usage And Synthesis

Uses

Ethyl Cis-?3-?iodoacrylate is a reactant used in the synthesis of complex naphtho(benzo)furans as well as in the cobalt-catayzed cross coupling of functionalized organozinc pivalates.

Uses

Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:

  • vinyl sulfides
  • (Z)-1-iodohept-1-en-3-ol
  • (E)-1-iodohept-1-en-3-ol
  • (Z)-β-iodoacrolein
  • 6-oxo-M1Guo

General Description

Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.

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