Tributyl(2-phenylethenyl)stannane
Tributyl(2-phenylethenyl)stannane Basic information
- Product Name:
- Tributyl(2-phenylethenyl)stannane
- Synonyms:
-
- (2-Phenylethenyl)tributylstannane
- [2-(Tributylstannyl)ethenyl]benzene
- 1-(Tributylstannyl)-2-phenylethene
- Styryltributylstannane
- Tributyl(2-phenylethenyl)stannane
- Tributyl(styryl)stannane
- tributyl(3-phenyl-2-propen-1-yl)Stannane
- Stannane, tributyl(3-phenyl-2-propen-1-yl)-
- CAS:
- 19752-27-3
- MF:
- C21H36Sn
- MW:
- 407.22
- Mol File:
- 19752-27-3.mol
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Tributyl(2-phenylethenyl)stannane Chemical Properties
- Boiling point:
- 426.8±48.0 °C(Predicted)
- alpha
- n20D 1.5185
- solubility
- sol THF, methylene chloride, chloroform.
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Tributyl(2-phenylethenyl)stannane Usage And Synthesis
Uses
Tributyl(2-phenylethenyl)stannane is a phenylallylating agent as an anion equivalent; 3-carbon component in a [3 + 2] cycloaddition reaction with α,β-unsaturated acylirons.
Preparation
Preparative Methods of Tributyl(2-phenylethenyl)stannane: by the coupling reaction of trans-cinnamylmagnesium bromide with Tri-n-butylchlorostannane (10-20%) or trapping of the lithiated derivative of allylbenzene (s-BuLi in cyclohexane/TMEDA/THF) with tributylchlorostannane at -78 °C (90%).
Tributyl(2-phenylethenyl)stannaneSupplier
Amadis Chemical Company Limited
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