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DIPHENYLCHLOROSILANE

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DIPHENYLCHLOROSILANE Basic information

Product Name:
DIPHENYLCHLOROSILANE
Synonyms:
  • chlorodiphenyl-silan
  • Diphenylsilyl chloride
  • Silane, chlorodiphenyl-
  • CHLORODIPHENYLSILANE
  • DIPHENYLCHLOROSILANE
  • Diphenylchlorosilane (PURITY??)
  • CHLORODIPHENYLSILANE, TECH., 90%
  • Chlorodiphenylsilane, 90+%
CAS:
1631-83-0
MF:
C12H11ClSi
MW:
218.75
EINECS:
216-634-8
Mol File:
1631-83-0.mol
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DIPHENYLCHLOROSILANE Chemical Properties

Boiling point:
143 °C10 mm Hg(lit.)
Density 
1.118 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.578(lit.)
Flash point:
>230 °F
solubility 
sol benzene, chloroform, carbon tetrachloride, and ether.
Specific Gravity
1.118
Water Solubility 
Reacts with water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
2937164
InChIKey
VTMOWGGHUAZESJ-UHFFFAOYSA-N
CAS DataBase Reference
1631-83-0(CAS DataBase Reference)
EPA Substance Registry System
Silane, chlorodiphenyl- (1631-83-0)
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Safety Information

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-28-36/37/39-45
RIDADR 
UN 2987 8/PG 2
WGK Germany 
1
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090

MSDS

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DIPHENYLCHLOROSILANE Usage And Synthesis

Physical properties

bp 140–145°C/7 mmHg (99–101°C/1 mmHg; 83–85°C/0.4 mmHg); d 1.137 g cm?3; n 1.5845.

Uses

Chlorodiphenylsilane is used in Medicine field, electronics industry, polymer materials. It is used in reduction of alcohols.

Uses

Organolithium and Grignard reagents react with chlorodiphenylsilane to produce substituted alkyl- or aryldiphenylsilanes (eqs 4 and 5).

Preparation

chlorodiphenylsilane may be prepared in high yield by treatment of diphenylsilane with triphenylmethyl chloride in refluxing benzene or with PCl5 at rt in CCl4.

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