4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Basic information
- Product Name:
- 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
- Synonyms:
-
- 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
- 4-METHYL-1,2,4 TRIAUZOLINE 3,5-DIONE
- N-Methyl-1,2,4-triazolinedione
- 4-Methyl-1,2,4-triazolinedione
- N-Methyl-1,2,4-triazoline-3,5-dione
- N-Methyl-1,3,4-triazoline-2,5-dione
- 3H-1,2,4-Triazole-3,5(4H)-dione, 4-Methyl-
- 4-methyl-1,2,4-triazole-3,5-dione
- CAS:
- 13274-43-6
- MF:
- C3H3N3O2
- MW:
- 113.07
- Product Categories:
-
- Heterocyclic Compounds
- Building Blocks
- Heterocyclic Building Blocks
- Triazoles
- Heterocycles
- Intermediates & Fine Chemicals
- Pharmaceuticals
- Mol File:
- 13274-43-6.mol
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4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Chemical Properties
- Melting point:
- 107-109 °C(lit.)
- Boiling point:
- 137.5±23.0 °C(Predicted)
- Density
- 1.71±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- DMSO (Slightly), Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol
- form
- Solid
- pka
- -3.61±0.20(Predicted)
- color
- Pink to Dark Pink
- Stability:
- Hygroscopic, Temperature Sensitive, Unstable in Solution
MSDS
- Language:English Provider:SigmaAldrich
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4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Usage And Synthesis
Uses
4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE is a dienophile used in the partial elucidation of Trichogramma putative sex pheromone at trace levels.
Synthesis Reference(s)
The Journal of Organic Chemistry, 31, p. 3444, 1966 DOI: 10.1021/jo01348a532
Synthetic Communications, 17, p. 409, 1987 DOI: 10.1080/00397918708063918
Purification Methods
MTAD is obtained as pink needles by sublimation at 40-50o/0.1mm (see 4-phenyl-1,2,4-triazoline-3,5-dione, PTAD below). [Cookson et al. Org Synth 51 121 1971, Cheng et al. J Org Chem 49 2910 1984, Beilstein 26 III/IV 538.]
4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONESupplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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- 021-50135380
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Hangzhou Sage Chemical Co., Ltd.
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Jiaxing Novartis Chemical Co., Ltd.
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- 18957373295
Amadis Chemical Company Limited
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- 571-89925085
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4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE(13274-43-6)Related Product Information
- 4-PHENYL-1,2,4-TRIAZOLINE-3,5-DIONE
- 4-(2-CHLORO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE
- 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
- 4-(4-BROMO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE
- 4-(4-METHOXY-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE
- 4-(4-FLUORO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE
- 4-CYCLOHEXYL-[1,2,4]TRIAZOLE-3,5-DIONE
- 4-P-TOLYL-[1,2,4]TRIAZOLE-3,5-DIONE
- DMEQ-TAD
- 4-(4-CHLORO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE