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1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

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1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Basic information

Product Name:
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
Synonyms:
  • 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
  • 1,1,1-TRIMETHYLHYDRAZONIUM IODIDE
  • 1,1,1-trimethyl-hydraziniuiodide
  • 1,1,1-trimethyl-hydrazoniuiodide
  • 1,1,1-triMethylhydrazin-1-iuM iodide
  • 1,1,1-TriMethylhydraziniuM iodide 97%
  • Mildronate Impurity 1
  • amino(trimethyl)azanium:iodide
CAS:
3288-80-0
MF:
C3H11IN2
MW:
202.04
Product Categories:
  • Hydrazines
  • Nitrogen Compounds
  • Organic Building Blocks
Mol File:
3288-80-0.mol
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1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Chemical Properties

Melting point:
225-230 °C (dec.) (lit.)
EPA Substance Registry System
1,1,1-trimethylhydrazinium iodide (3288-80-0)
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Safety Information

Hazard Codes 
T
Risk Statements 
61-36/37/38
Safety Statements 
53-36/37/39-45
WGK Germany 
3
RTECS 
MW0349100
HS Code 
2928009090

MSDS

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1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Usage And Synthesis

Uses

1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.

General Description

1,1,1-Trimethylhydrazinium iodide ([(CH3)3N-NH2]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH3)3N-NH2][NO3]), perchlorate ([(CH3)3N-NH2][ClO4]), azide ([(CH3)3N-NH2][N3]), 5-amino-1H-tetrazolate ([(CH3)3N-NH2][H2N-CN4]) and sulfate ([(CH3)3N-NH2]2[SO4].2H2O).

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