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AMINOTRIPHENYLSILANE

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AMINOTRIPHENYLSILANE Basic information

Product Name:
AMINOTRIPHENYLSILANE
Synonyms:
  • 1,1,1-TRIPHENYLSILYLAMINE
  • AMINOTRIPHENYLSILANE
  • TPSA
  • TRIPHENYLSILYLAMINE
  • TRIPHENYLAMINOSILANE
  • Triphenylsilanamine
  • [amino-di(phenyl)silyl]benzene
  • [azanyl-di(phenyl)silyl]benzene
CAS:
4215-80-9
MF:
C18H17NSi
MW:
275.42
EINECS:
224-147-7
Product Categories:
  • Building Blocks
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Protected Amines
Mol File:
4215-80-9.mol
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AMINOTRIPHENYLSILANE Chemical Properties

Melting point:
60-62 °C(lit.)
Boiling point:
187-200 °C(Press: 2 Torr)
Density 
1.10±0.1 g/cm3(Predicted)
storage temp. 
−20°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
6.31±0.70(Predicted)
form 
Solid
color 
White to Off-White
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Stability:
Hygroscopic, Moisture Sensitive
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
10-21
TSCA 
No
HS Code 
2931900090

MSDS

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AMINOTRIPHENYLSILANE Usage And Synthesis

Uses

Triphenylsilylamine is used as a reagent to produce 2-Amino-3-hydroxy-indoles with potent in vivo antimalarial activity. Triphenylsilylamine is also used to modify Mo/HZSM-5 catalysts and is predicted to have effects on selectivity in the methane-to-benzene (MTB) reaction.

Uses

Triphenylsilylamine may be used in the following studies:

  • Preparation of dimers of the type [Ti(μ-NR)(NMe2)2]2 (R = 1-adamantyl, (t)Bu, SiPh3).
  • Silylation during the pretreatment of fused silica capillary surface to achieve a homogeneous film.
  • Preparation of triphenylsilylsulfinylamine, via reaction with thionylchloride.
  • To investigate the molecular tuning effect of silanation treatment for HZSM-5 crystals.
  • Synthesis of 9-aminopyrido[3′,3′:4,5]pyrrolo[1,2-c]pyrimidine (9-aminosubstituted derivative).

General Description

Triphenylsilylamine is a silyl compound.

AMINOTRIPHENYLSILANESupplier

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