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Boron sub-2,3-naphthalocyanine chloride

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Boron sub-2,3-naphthalocyanine chloride Basic information

Product Name:
Boron sub-2,3-naphthalocyanine chloride
Synonyms:
  • SUBNC
  • 16-chloro-2,15,17,30,42,43-hexaaza-16-boraundecacyclo[29.10.1.11?,1?.03,1?.0?,13.0?,11.01?,2?.01?,2?.021,2?.032,?1.03?,3?]tritetraconta-1,3,5,7,9,11,13,18(43),19,21,23,25,27,29,31(42),32,34,36,38,40-icosaene
  • BORON SUB-2,3-NAPHTHALOCYANINE CHLORIDE
CAS:
142710-56-3
MF:
C36H18BClN6
MW:
580.84
Product Categories:
  • Organic Electronics and Photonics
  • Photonic and Optical Materials
  • Infrared (IR) DyesPhotonic and Optical Materials
  • Phthalocyanine and Porphyrin Dyes
  • Phthalocyanines
Mol File:
142710-56-3.mol
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Boron sub-2,3-naphthalocyanine chloride Chemical Properties

Melting point:
270-276 °C(lit.)
InChIKey
NLJNQWBWPGLVBY-UHFFFAOYSA-N
SMILES
[Cl-][B+3]12N3=C4C5C=C6C=CC=CC6=CC=5C3=NC3=C5C=C6C=CC=CC6=CC5=C(N=C5C6C=C7C=CC=CC7=CC=6C(=N4)[N-]15)[N-]23
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Safety Information

WGK Germany 
3
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Boron sub-2,3-naphthalocyanine chloride Usage And Synthesis

Description

Due to its thermal stability, boron sub-2,3- naphthalocyanine chloride (SubNc) has been studied as a photoactive material for PV cells. In addition, a SubNc film exhibits strong absorption in the red light region. SubNc had been investigated as a potential red-sensitive organic photoconductive film (OPF). A photoconductive cell was fabricated, and its current-voltage characteristics, both with and without light irradiation, and external quantum efficiency (EQE) were determined. SubNc film absorbed light in the red region well, with an absorption peak at 695 nm. The EQE of the cell reached 80% when the applied bias was 15 V. In addition, the blocking layers effectively suppressed dark current in the OPF, corresponding to a current density of 20 nA/cm2 at 15 V. These results indicate that SubNc is a promising candidate as a red-sensitive OPF[1].

References

[1] T. Sakai. “Highly Sensitive Organic Photoconductor Using Boron Sub-2,3-naphthalocyanine as a Red-sensitive Film for Stack-type Image Sensors.” MRS Advances 1 1 (2016): 459–464.

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