ChemicalBook > Product Catalog > Catalyst and Auxiliary > Precious Metal Catalysts > Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) Basic information
- Product Name:
- Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
- Synonyms:
-
- Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
- Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) (ACI)
- Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-3'-sodiumsulfonato-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),sSPhosPdG2
- 2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-Palladate(1-) sodium (1:1) (ACI)
- 2'-(Amino-kappan)-biphenyl-2-yl-kappac]chloro[2'-(dicyclohexylphosphino-kappap)-2,6-dimethoxy-biphenyl-3-sulfonato]-palladate(I) sodium
- CAS:
- 2375242-78-5
- MF:
- C38H44ClNO5PPdS.Na
- MW:
- 822.67
- Mol File:
- 2375242-78-5.mol
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Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) Chemical Properties
- Melting point:
- 193-194 °C (decomposition)
- storage temp.
- 2-8°C, sealed storage, away from moisture
- form
- solid
- color
- Light brown to brown
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Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) Usage And Synthesis
Uses
sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:
- DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates.
- DNA-compatible hydroxycarbonylation reactions.
- The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)Supplier
Wuhan Taiyu New Materials Co., Ltd. Gold
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Shaanxi Rock New Materials Co., Ltd.
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Shanghai Haozhixiang Biotechnology Co., Ltd
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Shanghai YuanYe Biotechnology Co., Ltd.
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Tianjin Kailiqi Biotechnology Co., Ltd.
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- 15076683720
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