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Bis(3- salicylideneaminopropyl)aminecobalt(II)

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Bis(3- salicylideneaminopropyl)aminecobalt(II) Basic information

Product Name:
Bis(3- salicylideneaminopropyl)aminecobalt(II)
Synonyms:
  • AIDS030597
  • Bis(3- salicylideneaminopropyl)aminecobalt(II)
CAS:
15306-22-6
MF:
C20H22CoN3O2
MW:
395.35
Mol File:
15306-22-6.mol
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Bis(3- salicylideneaminopropyl)aminecobalt(II) Chemical Properties

storage temp. 
store in a sealed container under an inert atmosphere.
solubility 
sol MeOH, CH2Cl2, CHCl3, C6H6, THF, C5H5N and DMF
color 
green crystals
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Bis(3- salicylideneaminopropyl)aminecobalt(II) Usage And Synthesis

Uses

Bis(3-salicylideneaminopropyl)aminecobalt(II) is a catalyst for the homogeneous oxygenation of phenols with dioxygen in organic media.

Synthesis

Bis(3-salicylideneaminopropyl)aminecobalt(II) is prepared under nitrogen from bis(salicylaldehydehydato)cobalt(II) dihydrate and bis(3- aminopropyl)amine. The long green prisms are collected by suction, washed with cold methanol, and dried in a vacuum desiccator. May be recrystallized from methanol if necessary; normally used without further purification.

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