Basic information Safety Supplier Related

1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate

Basic information Safety Supplier Related

1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate Basic information

Product Name:
1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate
Synonyms:
  • 2-(Diphenylphosphino)terephthalic acid 1-methyl 4-pentafluorophenyl diester 97%
  • 1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate
  • 2-(Diphenylphosphino)terephthalic acid 1-methyl 4-pentafluorophenyl diester
MF:
C27H16F5O4P
MW:
530.379317
Mol File:
Mol File
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1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate Chemical Properties

Melting point:
109-111 °C
storage temp. 
-20°C
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1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate Usage And Synthesis

Uses

  • Staudinger ligation reagent for the conjugation of amine and azide containing compounds or biomolecules.
  • The amine functionalized molecule first reacts with the phosphine through the activated pentafluorophenyl ester.The azide-molecule is then reacted with the newly labeled phosphine to form the iminophosphorane, and the aza-ylide is subsequently captured by the methyl ester to yield the covalent conjugated product.

The Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic Method

1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylateSupplier

Sigma-Aldrich
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