Basic information Safety Supplier Related

E-1-OCTENYLBORONIC ACID

Basic information Safety Supplier Related

E-1-OCTENYLBORONIC ACID Basic information

Product Name:
E-1-OCTENYLBORONIC ACID
Synonyms:
  • TRANS-OCTENYLBORONIC ACID
  • TRANS-1-OCTEN-1-YLBORONIC ACID
  • RARECHEM AL BA 0034
  • E-1-OCTENYLBORONIC ACID
  • E-OCTEN-1-YLBORONIC ACID
  • trans-1-Octenylboronic acid, 98%
  • (2E)-2-Octen-1-ylboronic acid
  • (E)-1-Octen-1-ylboronic acid
CAS:
42599-16-6
MF:
C8H17BO2
MW:
156.03
Product Categories:
  • Alkenyl Boronic Acids
  • Boronic Acids
  • blocks
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Organometallic Reagents
  • BoronicAcids
  • Alkenyl
  • Boronic Acids
  • Boronic Acids and Derivatives
Mol File:
42599-16-6.mol
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E-1-OCTENYLBORONIC ACID Chemical Properties

Melting point:
100-104 °C(lit.)
Boiling point:
263.2±23.0 °C(Predicted)
Density 
0.911±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Store in freezer, under -20°C
pka
9.84±0.43(Predicted)
Water Solubility 
Insoluble in water. Soluble in organic solvents.
CAS DataBase Reference
42599-16-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2931900090

MSDS

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E-1-OCTENYLBORONIC ACID Usage And Synthesis

Uses

Reactant for:• ;Chiral palladacycle-catalyzed asymmetric ring-opening reaction1• ;Enantioselective conjugate addition catalyzed by acyltartaric acids2• ;Copper-mediated oxidative cross-coupling reactions3• ;Diastereoselective domino Heck-Suzuki reactions4

Uses

trans-1-Octenylboronic acid, is used as a reagent of boronic esters in Suzuki-Miyaura cross-couplings.

Synthesis Reference(s)

Journal of the American Chemical Society, 95, p. 5786, 1973 DOI: 10.1021/ja00798a071

E-1-OCTENYLBORONIC ACIDSupplier

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