Basic information Safety Supplier Related

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

Basic information Safety Supplier Related

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Basic information

Product Name:
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
Synonyms:
  • (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene
  • (2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE
  • (SP,S'P)-1,1'-Bis[(R)-aL
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe
  • (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
  • ]-2,2'-bis(diphenyL
  • (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
  • (S,S)Fc-1,1’- Bis(diphenylphosphino)-2,2'- bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]fer rocene
CAS:
174467-31-3
MF:
C52H48FeN2P2
MW:
818.76
Mol File:
174467-31-3.mol
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Chemical Properties

alpha 
-320.0° (c 1.0, CHCl3)
form 
solid
color 
orange-red
Stability:
store cold
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Safety Information

WGK Germany 
3
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Usage And Synthesis

Uses

Chlorotricarbonyl(4,4'-di-t-butyl-2,2'-bipyridine)rhenium(I) is used for the reduction of carbon dioxide as a catalyst.

Reactions

  1. Ligand used for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with methyl 4-bromobenzoate.
  2. Ligand used for the gold-catalyzed phenol synthesis from furyldialkyne.
  3. Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [( 6 -benzylamine)Cr(CO)3]
  4. Ligand used for the palladium-catalyzed asymmetric synthesis of α-allyl-α-aryl α-amino acids by tandem alkylation/π-allylation of α-iminoesters

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferroceneSupplier

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