1-DIMETHYLAMINO-2-NITROETHYLENE
1-DIMETHYLAMINO-2-NITROETHYLENE Basic information
- Product Name:
- 1-DIMETHYLAMINO-2-NITROETHYLENE
- Synonyms:
-
- 1-(N,N-Dimethylamino)-2-nitroethylene
- 1-Nitro-2-(dimethylamino)ethylene
- N-(2-Nitrovinyl)dimethylamine
- N,N-Dimethyl-2-nitrovinylamine
- DiMethylaMino nitroethylene
- EthenaMine, N,N-diMethyl-2-nitro-
- N,N-dimethyl-2-nitroethen-1-amine
- (E)-N,N-dimethyl-2-nitroethen-1-amine
- CAS:
- 1190-92-7
- MF:
- C4H8N2O2
- MW:
- 116.12
- EINECS:
- 628-409-5
- Mol File:
- 1190-92-7.mol
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1-DIMETHYLAMINO-2-NITROETHYLENE Chemical Properties
- Melting point:
- 103-107 °C(lit.)
- Boiling point:
- 161℃
- Density
- 1.073
- Flash point:
- 51℃
- storage temp.
- 2-8°C
- solubility
- sol alcohols, ethers, chloroform, acetone; slightly sol n-hexane
- form
- crystalline solid
- pka
- 2.71±0.70(Predicted)
- color
- Orange
- BRN
- 1903136
- InChI
- InChI=1S/C4H8N2O2/c1-5(2)3-4-6(7)8/h3-4H,1-2H3
- InChIKey
- JKOVQYWMFZTKMX-ONEGZZNKSA-N
- SMILES
- C(N(C)C)=C[N+]([O-])=O
- CAS DataBase Reference
- 1190-92-7(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-37/38-41-43
- Safety Statements
- 26-36/37/39-45
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- IRRITANT, KEEP COLD
- HS Code
- 29211990
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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1-DIMETHYLAMINO-2-NITROETHYLENE Usage And Synthesis
Uses
1-Dimethylamino-2-nitroethylene is widely used in organic reactions.
Uses
1-(Dimethylamino)-2-nitroethylene undergoes addition-elimination reaction with indoles to form the corresponding 3-(2-nitrovinyl)indoles.
Preparation
1-Dimethylamino-2-nitroethylene can be prepared by reaction of N,N-Dimethylformamide Diethyl Acetal (85% yield) or N,N-Dimethylformamide-Dimethyl Sulfate complex (60%) with Nitromethane; condensation of Triethyl Orthoformate with MeNO2 in the presence of DMF (52%), or addition-elimination reaction of 1-Nitro-2-phenylthioethylene with Me2NH (74%).
1-DIMETHYLAMINO-2-NITROETHYLENESupplier
Struchem Co., Ltd. Gold
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- 0512-63009836 18994340901
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J & K SCIENTIFIC LTD.
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- 18210857532; 18210857532
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- 4006356688 18621169109
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Alfa Aesar
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- 400-6106006
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Energy Chemical
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- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
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1-DIMETHYLAMINO-2-NITROETHYLENE(1190-92-7)Related Product Information
- 1-DIMETHYLAMINO-2-NITROETHYLENE
- Nitroethylene
- N,1-DIMETHYL-6-MORPHOLINO-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINAMINE
- 4-[1-METHYL-6-(METHYLAMINO)-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINYL]-N-PHENYLTETRAHYDRO-1(2H)-PYRAZINECARBOXAMIDE
- N,1-DIMETHYL-6-[4-(METHYLSULFONYL)PIPERAZINO]-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINAMINE
- N,1-DIMETHYL-6-(METHYLSULFANYL)-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINAMINE
- N-(4-CHLOROBENZYL)-N-[1-METHYL-6-(METHYLAMINO)-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINYL]AMINE
- 1,3,6-Trimethyl-5-nitrouracil
- AKOS BC-1513
- N,1-DIMETHYL-3,5-DINITRO-6-[4-(PHENYLSULFONYL)PIPERAZINO]-1,4-DIHYDRO-2-PYRIDINAMINE
- SPECS AB-323/25048251
- 1-(4-[2,6-DINITRO-4-(TRIFLUOROMETHYL)PHENYL]PIPERAZINO)-2-NITROVINYL METHYL SULFIDE
- N-(4-CHLOROPHENYL)-4-[1-METHYL-6-(METHYLAMINO)-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINYL]TETRAHYDRO-1(2H)-PYRAZINECARBOXAMIDE
- SPECS AB-323/25048288
- 3-METHYL-2-(NITROMETHYLENE)-5-(3-OXO-1,3-DIHYDRO-2-BENZOFURAN-1-YL)-1,3-THIAZOLAN-4-ONE
- N-METHYL-N-(1-METHYL-3,5-DINITRO-6-[(2-PYRIDINYLMETHYL)AMINO]-1,4-DIHYDRO-2-PYRIDINYL)AMINE
- 4-[1-METHYL-6-(METHYLAMINO)-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINYL]-N-[3-(TRIFLUOROMETHYL)PHENYL]TETRAHYDRO-1(2H)-PYRAZINECARBOXAMIDE
- (4-[1-METHYL-6-(METHYLAMINO)-3,5-DINITRO-1,4-DIHYDRO-2-PYRIDINYL]PIPERAZINO)(PHENYL)METHANONE