NICKEL IODIDE
NICKEL IODIDE Basic information
- Product Name:
- NICKEL IODIDE
- Synonyms:
-
- NICKEL(II) IODIDE
- NICKEL IODIDE
- NICKEL IODIDE (OUS)
- nickel(2+)iodide
- nickeldiiodide
- nickeliodide(nii2)
- nickeliodide(nii2)[qr]
- nickelousiodide
- CAS:
- 13462-90-3
- MF:
- I2Ni
- MW:
- 312.5
- EINECS:
- 236-666-6
- Product Categories:
-
- Crystal Grade Inorganics
- Materials Science
- Metal and Ceramic Science
- Nickel
- Nickel Salts
- Catalysis and Inorganic Chemistry
- Crystal Grade Inorganics
- Metal and Ceramic Science
- Nickel Salts
- NickelMetal and Ceramic Science
- Salts
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Chemical Synthesis
- metal halide
- Mol File:
- 13462-90-3.mol
NICKEL IODIDE Chemical Properties
- Melting point:
- 797 °C(lit.)
- Boiling point:
- sublimes [LID94]
- Density
- 5.83 g/mL at 25 °C(lit.)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- H2O: slightly soluble(lit.)
- form
- Powder
- color
- black
- Specific Gravity
- 5.834
- Water Solubility
- Soluble in water and alcohols.
- Sensitive
- Hygroscopic
- Merck
- 13,6535
- Exposure limits
- ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 - Stability:
- hygroscopic
- CAS DataBase Reference
- 13462-90-3(CAS DataBase Reference)
- EPA Substance Registry System
- Nickel iodide (NiI2) (13462-90-3)
Safety Information
- Hazard Codes
- T
- Risk Statements
- 45-61-42/43
- Safety Statements
- 53-22-26-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 2827600090
- Hazardous Substances Data
- 13462-90-3(Hazardous Substances Data)
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
NICKEL IODIDE Usage And Synthesis
Chemical Properties
Black, crystalline powder or blue-green crystals; hygroscopic.Soluble in alcohol and water.
Uses
Strongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.1
Uses
Nickel Diiodide is used in preparation of Nickel complexes for migratory reductive cross-coupling.
Uses
Strongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.
Preparation
Nickel iodide can be prepared by dehydration of the hexahydrate or by the metathetic reaction between sodium iodide and nickel(II) chloride or nitrate in ethanol. It has the CdCl2 type lattice and is paramagnetic down to 75°K. Only one hydrate is well characterized—the blue-green NiI2?6H20 ; unlike the other halide hexahydrates, this contains [Ni(H2O)6]2+ cations.
Hazard
Toxic by ingestion.
NICKEL IODIDESupplier
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NICKEL IODIDE(13462-90-3)Related Product Information
- NICKEL SULFIDE
- Nickel sulfate
- Zinc sulfide
- MANGANESE(II) IODIDE
- Cadmium iodide
- Nickel carbonate
- NICKEL OXALATE DIHYDRATE
- Iodine
- IRON (II) IODIDE
- COBALT(II) IODIDE
- Cuprous iodide
- NICKEL BROMATE
- Cuprous iodide
- Nickel(II) iodide hexahydrate
- NICKEL IODIDE
- BIS(TRIPHENYLPHOSPHINE)NICKEL(II) IODIDE
- Nickel
- HEXAAMINENICKEL(II) IODIDE