Basic information Reactions Safety Supplier Related

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)

Basic information Reactions Safety Supplier Related

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Basic information

Product Name:
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
Synonyms:
  • 1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),Min.97%
  • 1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),97% (DPPE)CoCl2
  • Dichloro[ethylenebis[diphenylphosphine]]cobalt
  • [1,2-BIs(diphenylphosphino)
  • ethane]dichlorocobalt(II)
  • (1,2-bis(diphenylphosphino)ethane)-dichlorocobalt
  • [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
  • [1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ)
CAS:
18498-01-6
MF:
C26H26Cl2CoP2
MW:
530.27
Product Categories:
  • Co
  • Catalysis and Inorganic Chemistry
  • API intermediates
  • Chemical Synthesis
  • Cobalt
  • metal-phosphine complex
Mol File:
18498-01-6.mol
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[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Chemical Properties

Melting point:
260 °C (dec.)(lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
green
Water Solubility 
Insoluble in water.
Sensitive 
Hygroscopic
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3

MSDS

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[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Usage And Synthesis

Reactions

  1. Catalyst used for the hydrovinylation of styrene.
  2. Cobalt-catalyzed hydroalkylation of [60] fullerene with active alkyl bromides.
  3. Cobalt-catalyzed 1,4-addition of organoboronic acids to activated alkenes. 

Uses

Dichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II) is used as a catalyst for regio- and stereoselective intermolecular enzyme coupling, cross-coupling reactions of alkyl halides with aryl Grignard reagents, hydrovinylation of styrene, tandem radical cyclization and cross-coupling, dimethylation, hydrodechlorination and addition reactions.

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)Supplier

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