FERRIC THIOCYANATE Chemical Properties

solubility 

soluble in H2O, ethanol, acetone; itol, chloroform

form 

red hygroscopic crystals

color 

red-violet hygroscopic crystals, crystalline

Water Solubility 

soluble H2O, alcohol, ether, acetone, pyridine; insoluble CHCl3, toluene [MER06]

FERRIC THIOCYANATE Usage And Synthesis

Chemical Properties

cub red crystal(s); deliquescent; decomposes on heating [MER06] [CRC10]

Uses

?Iron Thiocyanate reacts with trialkylboranes to give alkyl thiocyanates; thiocyanation of unsaturated acids and esters.

Preparation

Though the simple cyanide Fe(CN)3 is unknown, the thiocyanate is prepared as dark violet crystals by reaction of thiocyanogen with iron or by extracting a mixture of potassium thiocyanate and an iron(III) salt with ether, followed by evaporation of the ether. It is very soluble in water from which it crystallizes as the red trihydrate Fe(SCN)3. 3H2O. The blood-red colour developed when dilute solutions of iron(III) salts and thiocyanate ions are mixed is due largely to the [Fe(SCN(H2O)5]²⁺ ion; this reaction finds extensive use in the qualitative and quantitative determination of iron.

storage

metal thiocyanates on heating to decomposition, or on contact with acid or acid fumes, emit highly toxic fumes.

FERRIC THIOCYANATE(4119-52-2)Related Product Information

• Cupric cyanide
• Potassium thiocyanate
• Sodium thiocyanate
• FERRIC THIOCYANATE