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DIMETHYLPHENYLSILANOL

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DIMETHYLPHENYLSILANOL Basic information

Product Name:
DIMETHYLPHENYLSILANOL
Synonyms:
  • DIMETHYLPHENYLSILANOL
  • Hydroxyphenyldimethylsilane
  • Phenylhydroxydimethylsilane
  • Phenyldimethylsilanol
  • Dimethylphenylsilanol,97%
  • Hydroxydimethylphenylsilane
  • Dimethylphenylsilanol 95%
  • Silanol, 1,1-dimethyl-1-phenyl-
CAS:
5272-18-4
MF:
C8H12OSi
MW:
152.27
EINECS:
693-848-1
Product Categories:
  • Chemical Synthesis
  • Organometallic Reagents
  • Phenyl Silanes
  • Organosilicon
  • Silanols
Mol File:
5272-18-4.mol
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DIMETHYLPHENYLSILANOL Chemical Properties

Boiling point:
60-62°C/0.5mm
Density 
0.975 g/mL at 25 °C
refractive index 
n 20/D 1.514
Flash point:
197 °F
storage temp. 
2-8°C
pka
14.17±0.53(Predicted)
Specific Gravity
0.97
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
EPA Substance Registry System
Silanol, dimethylphenyl- (5272-18-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36
Safety Statements 
26
WGK Germany 
3
TSCA 
Yes
HS Code 
29310099

MSDS

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DIMETHYLPHENYLSILANOL Usage And Synthesis

Chemical Properties

DIMETHYLPHENYLSILANOL is Colorless or yellowish transparent liquid

Uses

DIMETHYLPHENYLSILANOL is a useful silicon nucleophile for Pd-catalyzed cross-coupling.1

Uses

Dimethylphenylsilanol is an organosilanol that can be used:

  • As a coupling partner in the Pd(II) catalyzed Hiyama reaction for C5 C-H bond functionalization of 2,3-dihydropyridin-4(1H)-ones.
  • To introduce dimethylphenylsilyl end group on highly branched poly(dimethylsiloxane) polymers.
  • As a substrate in the Ru(0) catalyzed germasiloxanes synthesis by reacting with vinylgermanes.

DIMETHYLPHENYLSILANOLSupplier

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