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pipradrol

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pipradrol Basic information

Product Name:
pipradrol
Synonyms:
  • Detaril
  • Pipradol
  • di(phenyl)-(2-piperidyl)methanol
  • di(phenyl)-piperidin-2-ylmethanol
  • di(phenyl)-piperidin-2-yl-methanol
  • pipradrol
  • Azacyclononl
  • XSWHNYGMWWVAIE-UHFFFAOYSA-N
CAS:
467-60-7
MF:
C18H21NO
MW:
267.37
EINECS:
207-394-5
Mol File:
467-60-7.mol
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pipradrol Chemical Properties

Melting point:
81-82 °C(Solv: ethanol (64-17-5))
Boiling point:
410.55°C (rough estimate)
Density 
1.0449 (rough estimate)
refractive index 
1.5100 (estimate)
pka
pKa 9.71 (Uncertain)
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Safety Information

Hazardous Substances Data
467-60-7(Hazardous Substances Data)
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pipradrol Usage And Synthesis

Originator

Alertonic ,Adcock Ingram Ltd.

Definition

ChEBI: Pipradrol is a diarylmethane.

Manufacturing Process

A mixture of 48 g (0.167 mole) of α,α-diphenyl-2-pyridinemethanol hydrochloride (Emraert et al., Ber. 72B, 1188 (1939); 74B, 714 (1940), 160 ml of ethanol, and 3 0.5 g of Adams' platinum catalyst was shaken under an initial hydrogen pressure of 60 pounds. The theoretical amount of hydrogen was absorbed in 5 hours. The reaction mixture was refluxed, diluted with enough water to dissolve all the white solid, and filtered hot from the catalyst. The filtrate was cooled and filtered; yield of 38 g of α,α-diphenyl-alpha-(2piperidyl)methanol white product melting at 308-309°C with decomposition.
A mixture of 3.5 grams (0.013 mole) of the above α,α-diphenyl-alpha-(2piperidyl)methanol, 4 g (0.05 mole) of formaldehyde (37%), and 6 grams (0.1 mole) of formic acid was refluxed for 2 days. The reaction mixture was treated with 1.3 g (0.013 mole) of conc. hydrochloric acid and vacuum distilled on the steam bath. The residue was recrystallized from butanone to give the α,αdiphenyl-alpha-(2-piperidyl)methanol hydrochloride which melted at 228229°C (dec.).

brand name

Meratran (Marion Merrell Dow);Alertonic;Gerodryl;Leptidrol;Meratonic;Metadin;Peratran;Piridrol;Stimolag fortis.

Therapeutic Function

Central stimulant

World Health Organization (WHO)

Pipradrol, a central nervous system stimulant, was introduced in 1955 for use as an anorexic agent. Pipradrol is controlled under Schedule IV of the 1971 Convention on Psychotropic Substances. (Reference: (UNCPS4) United Nations Convention on Psychotropic Substances (IV), , , 1971)

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