Bis(4-methoxyphenyl)phosphine Chemical Properties

Melting point:

36-40°C

Boiling point:

352.4±42.0 °C(Predicted)

Flash point:

>110℃

form 

solid

InChI

1S/C14H15O2P/c1-15-11-3-7-13(8-4-11)17-14-9-5-12(16-2)6-10-14/h3-10,17H,1-2H3

InChIKey

FWKICRREDMVWRF-UHFFFAOYSA-N

SMILES

COc1ccc(Pc2ccc(OC)cc2)cc1

Safety Information

Hazard Codes 

F

Risk Statements 

11-36/37/38

Safety Statements 

26-36

RIDADR 

1325

WGK Germany 

3

HazardClass 

4.1

PackingGroup 

Ⅱ

Storage Class

4.1B - Flammable solid hazardous materials

Hazard Classifications

Eye Irrit. 2
Flam. Sol. 2
Skin Irrit. 2
STOT SE 3

Bis(4-methoxyphenyl)phosphine Usage And Synthesis

Uses

Reactant for:

• Enantioselective Ir-catalyzed hydrogenation
• Palladium-catalyzed asymmetric additions
• Alkali-metal-catalyzed addition reactions
• Preparation of different DIOP-type ligands for uses in Rh-catalyzed asymmetric hydrogenation

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reagent type: ligand