(11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin] SaxS,S-BOBPHOS
(11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin] SaxS,S-BOBPHOS Basic information
- Product Name:
- (11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin] SaxS,S-BOBPHOS
- Synonyms:
-
- (11AS)-1,2,10,11-TETRAMETHYL-4,8-BIS(T-BUTYL)-6-[[(2S,5S)-(2,5-DIPHENYL-1-PHOSPHOLANYL)METHOXY]-DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN]SAXS,S-BOBPHOS
- (11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin]
- (11aS)-1,2,10,11-TetramethyL
- ) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin]
- )-6-[[(2S,5S)-(2,5-diphenyL
- -1-phosphoL
- -4,8-bis(t-butyL
- anyL
- CAS:
- 1373349-83-7
- MF:
- C41H50O3P2
- MW:
- 652.781422
- Mol File:
- 1373349-83-7.mol
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(11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin] SaxS,S-BOBPHOS Chemical Properties
- Boiling point:
- 711.7±60.0 °C(Predicted)
- form
- Powder
- color
- white microcrystal
- Sensitive
- moisture sensitive
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(11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin] SaxS,S-BOBPHOS Usage And Synthesis
Reactions
- Rhodium/phospholane catalysts for the unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes.
- An asymmetric hydroformylation catalyst that delivers branched aldehydes from alkyl alkenes.
Uses
(11aS)-4,8-Bis(1,1-Dimethylethyl)-6-[[(2S,5S)-2,5-diphenyl-1-phospholanyl]methoxy]-1,2,10,11-tetramethyldibenzo[d,f][1,3,2]dioxaphosphepin is used as a catalyst for the stereoselective preparation of branched aldehydes.
(11aS)-1,2,10,11-Tetramethyl-4,8-bis(t-butyl)-6-[[(2S,5S)-(2,5-diphenyl-1-phospholanyl) methoxy]-dibenzo[d,f][1,3,2]dioxaphosphepin] SaxS,S-BOBPHOSSupplier
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