Basic information Reaction Safety Supplier Related

(R)-(+)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine

Basic information Reaction Safety Supplier Related

(R)-(+)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine Basic information

Product Name:
(R)-(+)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine
Synonyms:
  • (R)-(+)-1-[(R)-2-(2'-DiphenyL
  • )ferrocenyL
  • (R)-(+)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDIPHENYLPHOSPHINE
  • (R)-1-[(R)-1- (Diphenylphosphino)ethyl]-2-[2- (diphenylphosphino)phenyl]ferro cene
  • (R)-(+)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine, Walphos SL-W002-1
  • (R)-(+)-1-[(R)-2-(2''-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine
CAS:
565184-32-9
MF:
C42H31FeP2
MW:
653.5
Mol File:
565184-32-9.mol
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(R)-(+)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine Chemical Properties

Melting point:
73-77 °C
alpha 
+14° ±1.5° (c 0.5, CHCl3)
form 
Powder
color 
orange
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(R)-(+)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldiphenylphosphine Usage And Synthesis

Reaction

  1. Ligand for Rh and Ru-catalzyed hydrogenation of alkenes and ketones.
  2. Rh-catalyzed intermolecular [4+2].
  3. Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and ketones.

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