(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Basic information
- Product Name:
- (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- Synonyms:
-
- (R)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAP&
- (R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl,98%
- 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHALENE
- 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHALENE
- (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- (R)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- (S)-(-)-2,2'-BIS(METHOXYMETHOXY)-1,1-BINAPHTHALENE
- CAS:
- 173831-50-0
- MF:
- C24H22O4
- MW:
- 374.43
- Product Categories:
-
- BINOL Series
- Chiral Oxygen
- BINOLs
- Chiral Catalysts, Ligands, and Reagents
- Privileged Ligands and Complexes
- Aromatics
- Other Ligands
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Chiral Reagents
- Intermediates & Fine Chemicals
- Pharmaceuticals
- Mol File:
- 173831-50-0.mol
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(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Chemical Properties
- Melting point:
- 92-96 °C(lit.)
- alpha
- +85° (c 0.22, CHCl3)
- Boiling point:
- 477.8±45.0 °C(Predicted)
- Density
- 1.182±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- soluble in Toluene
- form
- Powder
- color
- white
- optical activity
- [α]20/D +92°, c = 1% in chloroform
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Safety Information
- Hazard Codes
- Xi,N
- Risk Statements
- 41-50/53
- Safety Statements
- 26-39-60-61-36/39-25
- RIDADR
- UN 3077 9/PG 3
- WGK Germany
- 3
- HS Code
- 29093090
MSDS
- Language:English Provider:SigmaAldrich
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(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Usage And Synthesis
Reaction
Starting material for the preparation of a variety of 3,3'-substituted binaphthols.
Chemical Properties
Colorless solid
Uses
3- or 3,3′-di-substituted products can be obtained easily via ortho-metallation and subsequent treatment with an electrophile to give the corresponding BINOL derivatives.
Uses
An intermediate in the symmetric synthesis of BINOL-terpyridine ligands.
(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYLSupplier
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(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL(173831-50-0)Related Product Information
- (R)-(+)-2,2'-Dimethoxy-1,1'-binaphthalene
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- (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
- 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL-3,3'-DIYLDIBORONIC ACID
- (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL