5-Bromo-1H-Benzo[d]Imidazole-2-Carboxylic Acid Chemical Properties

Melting point:

206℃

Boiling point:

495℃

Density 

1.946

Flash point:

253℃

storage temp. 

Sealed in dry,Store in freezer, under -20°C

form 

powder

pka

1.30±0.30(Predicted)

color 

Yellow

InChI

InChI=1S/C8H5BrN2O2/c9-4-1-2-5-6(3-4)11-7(10-5)8(12)13/h1-3H,(H,10,11)(H,12,13)

InChIKey

ULTDLMITPWHISY-UHFFFAOYSA-N

SMILES

C1(C(O)=O)NC2=CC(Br)=CC=C2N=1

Safety Information

HS Code 

2933998090

5-Bromo-1H-Benzo[d]Imidazole-2-Carboxylic Acid Usage And Synthesis

Synthesis

General procedure for the synthesis of 5-bromobenzimidazole-2-carboxylic acid from 2-(hydroxymethyl)-5-bromobenzimidazole: 5-bromo-1H-benzimidazol-2-ylmethanol (0.23 g, 1.0 mmol) was dissolved in acetone (10 mL), and an aqueous solution of potassium permanganate (0.379 g, 2.4 mmol) was added (10 mL). After completion of the reaction, the crude product was recrystallized from water to give 5-bromo-1H-benzimidazole-2-carboxylic acid as a creamy white powder in 37% yield.

References

[1] Molecules, 2015, vol. 20, # 8, p. 15206 - 15223

5-Bromo-1H-Benzo[d]Imidazole-2-Carboxylic Acid(40197-20-4)Related Product Information

• 1H-Imidazole-2-carboxylic acid
• 5-Bromo-1H-benzimidazole
• 6-BROMO-1H-BENZOIMIDAZOLE-4-CARBOXYLIC ACID
• 5-BROMO-1H-BENZIMIDAZOLE-2-CARBOXYLIC ACID ETHYL ESTER
• 5-Bromo-1H-Benzo[d]Imidazole-2-Carboxylic Acid
• 6-BROMO-1H-BENZOIMIDAZOLE-2-CARBOXYLIC ACID METHYL ESTER
• 6-bromo-1H-benzo[d]imidazol-4-amine