(1S,4S,8S)-5-BENZYL-8-METHOXY-1,8-DIMETHYL-2-(2'-METHYLPROPYL)-BICYCLO [2.2.2]OCTA-2,5-DIENE Chemical Properties

Boiling point:

392.1±42.0 °C(Predicted)

Density 

1.00±0.1 g/cm3(Predicted)

refractive index 

n20/D1.522

form 

liquid

optical activity

[α]/D 84±5°, c = 0.5 in chloroform

InChI

1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m0/s1

InChIKey

ACWLDJOHMGJACE-BDTNDASRSA-N

SMILES

CO[C@@]1(C)C[C@@]2(C)C=C(Cc3ccccc3)[C@@H]1C=C2CC(C)C

Safety Information

WGK Germany 

3

Storage Class

10 - Combustible liquids

(1S,4S,8S)-5-BENZYL-8-METHOXY-1,8-DIMETHYL-2-(2'-METHYLPROPYL)-BICYCLO [2.2.2]OCTA-2,5-DIENE Usage And Synthesis

Uses

Carreira DOLEFIN Ligands

General Description

(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone.

reaction suitability

reaction type: click chemistry

(1S,4S,8S)-5-BENZYL-8-METHOXY-1,8-DIMETHYL-2-(2'-METHYLPROPYL)-BICYCLO [2.2.2]OCTA-2,5-DIENE(862499-50-1)Related Product Information

• menthane, tetradehydro derivative
• (1S,4S,8S)-5-BENZYL-8-METHOXY-1,8-DIMETHYL-2-(2'-METHYLPROPYL)-BICYCLO [2.2.2]OCTA-2,5-DIENE