Benzyldiphenylphosphine
Benzyldiphenylphosphine Basic information
- Product Name:
- Benzyldiphenylphosphine
- Synonyms:
-
- Benzyldiphenylphosphine,98%
- BENZYLDIPHENYLPHOSPHINE
- Benzyldiphenylphosphine,99%
- Diphenyl(phenylmethyl)phosphine
- Diphenylbenzylphosphine
- Benzyldiphenylphosphine,97%
- Phosphine, diphenyl(phenylmethyl)-
- CAS:
- 7650-91-1
- MF:
- C19H17P
- MW:
- 276.31
- EINECS:
- 1312995-182-4
- Product Categories:
-
- organophosphorus ligand
- Achiral Phosphine
- Basic Phosphine LigandsCatalysis and Inorganic Chemistry
- Catalysis and Inorganic Chemistry
- Cross-Coupling
- Aryl Phosphine
- Phosphine Ligands
- Phosphorus Compounds
- Mol File:
- 7650-91-1.mol
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Benzyldiphenylphosphine Chemical Properties
- Melting point:
- 77-83 °C (lit.)
- Boiling point:
- 205-208 °C(Press: 1.5 Torr)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- White to off-white
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Air Sensitive
- InChI
- InChI=1S/C19H17P/c1-4-10-17(11-5-1)16-20(18-12-6-2-7-13-18)19-14-8-3-9-15-19/h1-15H,16H2
- InChIKey
- UZCPNEBHTFYJNY-UHFFFAOYSA-N
- SMILES
- P(C1=CC=CC=C1)(C1=CC=CC=C1)CC1=CC=CC=C1
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26
- WGK Germany
- 3
- HS Code
- 29310099
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Benzyldiphenylphosphine Usage And Synthesis
Chemical Properties
White to off-white powder
Uses
suzuki reaction
Uses
Employed as a catalyst for Suzuki cross-coupling and antiarthritic agent (inhibitor of cathepsin B). It is also used as catalyst in pharmaceutical research.
Preparation
An acetato-bridged binuclear cyclopalladated complex of benzyldiphenylphosphine, [{Pd(C6H4CH2PPh2)(O2CMe)}], could been obtained by the reaction between the phosphine and palladium(II) acetate[1].
References
[1] Katsuma Hiraki, Toshinobu Uchiyama, Yoshio Fuchita. “Cyclopalladation of benzyldiphenylphosphine by palladium(II) acetate.” Inorganica Chimica Acta 69 (1983): Pages 187-190.
BenzyldiphenylphosphineSupplier
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Benzyldiphenylphosphine(7650-91-1)Related Product Information
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- Benzyltriphenylphosphonium chloride
- (4-ETHOXYBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
- (4-N-BUTOXYBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
- (3-METHYLBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE
- (2-METHYLBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE
- (4-METHOXYBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE
- [4-(BROMOMETHYL)BENZYL]TRIPHENYLPHOSPHONIUM BROMIDE
- (9-FLUORENYL)TRIPHENYLPHOSPHONIUM BROMIDE
- 1,2-BIS(DIPHENYLPHOSPHINOMETHYL)BENZENE
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- Benzyltriphenylphosphonium bromide
- BENZYLDIPHENYLPHOSPHINE
- (4-METHYLBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
- 4-METHYLBENZYL TRIPHENYLPHOSPHONIUM CHLORIDE
- (1-NAPHTHYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE
- (2-HYDROXYBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
- (4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE