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TIN(II) IODIDE

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TIN(II) IODIDE Basic information

Product Name:
TIN(II) IODIDE
Synonyms:
  • TIN(II) IODIDE
  • TIN(+2)IODIDE
  • TIN IODIDE
  • STANNOUS IODIDE
  • diiodotin
  • SnI2
  • stannousdiiodide
  • Tin iodide (SnI2)
CAS:
10294-70-9
MF:
I2Sn
MW:
372.52
EINECS:
233-667-3
Product Categories:
  • Crystal Grade Inorganics
  • Metal and Ceramic Science
  • Salts
  • Tin Salts
  • TinMetal and Ceramic Science
  • metal halide
Mol File:
10294-70-9.mol
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TIN(II) IODIDE Chemical Properties

Melting point:
320 °C (lit.)
Boiling point:
714 °C (lit.)
Density 
5.28 g/mL at 25 °C (lit.)
Flash point:
720°C
solubility 
Soluble in benzene, carbon disulfide, chloroform, and solutions of alkali chlorides and iodides.
form 
Powder
Specific Gravity
5.28
color 
orange to red
Water Solubility 
Soluble in benzene, carbon disulfide, chloroform, and solutions of alkali chlorides and iodides. Decomposes in water
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Merck 
14,8785
Exposure limits
ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
CAS DataBase Reference
10294-70-9(CAS DataBase Reference)
EPA Substance Registry System
Tin iodide (SnI2) (10294-70-9)
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Safety Information

Hazard Codes 
T
Risk Statements 
61-20/21/22-36/37/38-42/43
Safety Statements 
53-22-26-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
XQ3650000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28276000

MSDS

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TIN(II) IODIDE Usage And Synthesis

Chemical Properties

reddish orange powder(s); moisture sensitive; enthalpy of vaporization 105kJ/mol [CRC10] [STR93]

Uses

Tin(II) iodide is used to prepare organic-inorganic perovskite thin films which exhibit uniform surfaces and strong photoluminescence. It finds application as an analytical reagent in the determination of rhodium and iridium by spectrophotometry. It is also involved in the synthesis of CH3(CH2)11NH3]SnI3 which is a hybrid semiconductor with MoO3 type tin(II) iodide layers.

Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of I-. See also IODIDES and TIN COMPOUNDS.

TIN(II) IODIDESupplier

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