Basic information Safety Supplier Related

OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V)

Basic information Safety Supplier Related

OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V) Basic information

Product Name:
OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V)
Synonyms:
  • OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V)
  • Trichloro[methylenebis[diphenylphosphine]-P,P′]oxorhenium
CAS:
60260-17-5
MF:
C25H22Cl3OP2Re
MW:
692.96
Product Categories:
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhenium
Mol File:
Mol File
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OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V) Chemical Properties

form 
solid
InChI
1S/C25H22P2.3ClH.O.Re/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;;/h1-20H,21H2;3*1H;;/q;;;;;+3/p-3
InChIKey
SAVOOVLDSRTAGJ-UHFFFAOYSA-K
SMILES
Cl[Re](Cl)(Cl)=O.C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
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Safety Information

WGK Germany 
3
Storage Class
11 - Combustible Solids
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OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V) Usage And Synthesis

Uses

Catalyst for:

  • Epoxidation of olefins using hydrogen peroxide activated bicarbonate as an oxidant
  • Efficient reduction of aromatic sulfoxides
  • Regioselective coupling of propargyl alcohols with sulfonamides and carbamates
  • Cycloisomerization reactions

reaction suitability

core: rhenium
reagent type: catalyst

OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V)Supplier

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OXOTRICHLORO(BIS(DIPHENYLPHOSPHINO)METHANE)RHENIUM(V)(60260-17-5)Related Product Information