(S,S)-F-BINAPHANE
(S,S)-F-BINAPHANE Basic information
- Product Name:
- (S,S)-F-BINAPHANE
- Synonyms:
-
- (S,S)-F-BINAPHANE
- 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane
- 1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene
- 1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene
- 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene (S,S)-f-Binaphane
- 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene
- CAS:
- 544461-38-3
- MF:
- C54H32FeP2
- MW:
- 798.64
- Mol File:
- 544461-38-3.mol
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(S,S)-F-BINAPHANE Chemical Properties
- form
- Powder
- color
- yellow-brown
- Sensitive
- air sensitive, light sensitive
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(S,S)-F-BINAPHANE Usage And Synthesis
Reaction
- Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides [5] and cyclic Nsulfonylimines.
- Enantioselective, asymmetric organocatalyst for cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
- Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%)
- Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of α-imino anions.
- Ligand used in iridium-catalyzed, asymmetric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).
(S,S)-F-BINAPHANESupplier
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