Basic information Reaction Safety Supplier Related

(S,S)-F-BINAPHANE

Basic information Reaction Safety Supplier Related

(S,S)-F-BINAPHANE Basic information

Product Name:
(S,S)-F-BINAPHANE
Synonyms:
  • (S,S)-F-BINAPHANE
  • 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane
  • 1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene
  • 1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene
  • 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene (S,S)-f-Binaphane
  • 1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene
CAS:
544461-38-3
MF:
C54H32FeP2
MW:
798.64
Mol File:
544461-38-3.mol
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(S,S)-F-BINAPHANE Chemical Properties

form 
Powder
color 
yellow-brown
Sensitive 
air sensitive, light sensitive
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(S,S)-F-BINAPHANE Usage And Synthesis

Reaction

  1. Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides [5] and cyclic Nsulfonylimines.
  2. Enantioselective, asymmetric organocatalyst for cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
  3. Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%)
  4. Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of α-imino anions.
  5. Ligand used in iridium-catalyzed, asymmetric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).

(S,S)-F-BINAPHANESupplier

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