rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Basic information
- Product Name:
- rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
- Synonyms:
-
- RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
- RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE
- RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
- RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM
- (R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
- (S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
- DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV)
- DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
- CAS:
- 100163-29-9
- MF:
- C20H24Cl2Zr10*
- MW:
- 426.53
- Product Categories:
-
- metallocene
- Zr
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Zirconium
- Mol File:
- 100163-29-9.mol
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Chemical Properties
- Melting point:
- 267-271 °C(lit.)
- form
- Powder
- color
- white to pale yellow
- Sensitive
- moisture sensitive
Safety Information
- Hazard Codes
- C,Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-45-36
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
MSDS
- Language:English Provider:SigmaAldrich
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Usage And Synthesis
Stability
Stable under normal temperature and pressure, avoid contact with water and oxidants.
Storage
sealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources.
Chemical Properties
White to pale yellow powder,it can carry out catalytic reaction.
Uses
Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.
Uses
Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichlorideSupplier
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rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride(100163-29-9)Related Product Information
- Zirconium tetrachloride
- Cobalt chloride
- Dichloroacetic acid
- POLYETHYLENE, CHLORINATED
- Zirconium oxychloride
- Bis(ethylcyclopentadienyl)zirconium dichloride
- Bis(1-ethyl-2-methylcyclopentadienyl)zirconium dichloride
- Bis(1-propyl-3-methylcyclopentadienyl)zirconium dichloride
- BIS(CYCLOPENTADIENYL)ZIRCONIUM DIHYDRIDE
- Bis(cyclopentadienyl)zirconium dichloride
- BIS(N-PROPYLCYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE
- Bis(1-ethyl-3-methylcyclopentadienyl)zirconium dichloride
- Bis(1-butyl-3-methylcyclopentadienyl)zirconium dichloride
- ZIRCONYL CHLORIDE HYDRATE
- Bis(n-butylcyclopentadienyl)zirconium dichloride
- Zirconium
- Bis(methylcyclopentadienyl)zirconium dichloride
- BIS(1,3-DIMETHYLCYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE