DIETHYLPHOSPHORAMIDOUS DICHLORIDE
DIETHYLPHOSPHORAMIDOUS DICHLORIDE Basic information
- Product Name:
- DIETHYLPHOSPHORAMIDOUS DICHLORIDE
- Synonyms:
-
- DICHLORO(DIETHYLAMINO)PHOSPHINE
- (DIETHYLAMINO)PHOSPHONOUS DICHLORIDE
- (DIETHYLAMINO)DICHLOROPHOSPHINE
- DIETHYLPHOSPHORAMIDOUS DICHLORIDE
- N,N-Diethylphosphoramidous Dichloride
- Diethylphosphoramidous dichloride,97%
- (Diethylamido)dichlorophosphite
- (Diethylamino)phosphine dichloride
- CAS:
- 1069-08-5
- MF:
- C4H10Cl2NP
- MW:
- 174.01
- EINECS:
- 628-166-5
- Product Categories:
-
- wq
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Phosphorus Precursors
- Mol File:
- 1069-08-5.mol
DIETHYLPHOSPHORAMIDOUS DICHLORIDE Chemical Properties
- Boiling point:
- 179 °C (lit.)
- Density
- 1.196 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.497(lit.)
- Flash point:
- 181 °F
- storage temp.
- 2-8°C
- form
- Liquid
- pka
- -1.49±0.70(Predicted)
- color
- Clear colorless
- Water Solubility
- Reacts violently in water.
- Sensitive
- Moisture Sensitive
- InChI
- InChI=1S/C4H10Cl2NP/c1-3-7(4-2)8(5)6/h3-4H2,1-2H3
- InChIKey
- BPEMCEULJQTJMI-UHFFFAOYSA-N
- SMILES
- P(N(CC)CC)(Cl)Cl
- CAS DataBase Reference
- 1069-08-5(CAS DataBase Reference)
Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-43-45
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29310099
- Storage Class
- 8A - Combustible corrosive hazardous materials
- Hazard Classifications
- Skin Corr. 1B
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
DIETHYLPHOSPHORAMIDOUS DICHLORIDE Usage And Synthesis
Chemical Properties
DIETHYLPHOSPHORAMIDOUS DICHLORIDE is clear colorless to light yellow liquid
Uses
Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols.
Uses
Reagent for the preparation of diethylaminophosphine-metal complexes and the phosphitylation of alcohols.
Uses
DIETHYLPHOSPHORAMIDOUS DICHLORIDE is a useful reagent for the efficient phosphorylation of alcohols.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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