ChemicalBook > Product Catalog > Catalyst and Auxiliary > Precious Metal Catalysts > [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Basic information
- Product Name:
- [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
- Synonyms:
-
- [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
- [PdCl2{(R)-4-tolylbinap}]
- CAS:
- 191654-69-0
- MF:
- C48H42Cl2P2Pd
- MW:
- 858.13
- Mol File:
- 191654-69-0.mol
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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Chemical Properties
- Melting point:
- >300°C
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26
- WGK Germany
- 3
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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Usage And Synthesis
Uses
Catalyst for:
- Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal
- Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants
- Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc
Reactant for:
- Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chlorideSupplier
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