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N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

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N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Basic information

Product Name:
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
Synonyms:
  • Prop-2-en-1-ylbis(trimethylsilyl)amine
  • 1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine
  • Allylbis(trimethylsilyl)amine
  • α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine
  • Einecs 231-699-2
  • N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
  • N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
  • 2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&
CAS:
7688-51-9
MF:
C9H23NSi2
MW:
201.46
EINECS:
231-699-2
Product Categories:
  • Organometallic Reagents
  • Organosilicon
  • Others
Mol File:
7688-51-9.mol
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N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Chemical Properties

Boiling point:
72 °C/15 mmHg (lit.)
Density 
0.816 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.440(lit.)
Flash point:
109 °F
form 
liquid
Specific Gravity
0.817
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
16-26-36/37
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
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N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Usage And Synthesis

Uses

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:

  • Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
  • Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
  • Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.


AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINESupplier

Meryer (Shanghai) Chemical Technology Co., Ltd.
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BeiJing Hwrk Chemicals Limted
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Shanghai Hanhong Scientific Co.,Ltd.
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ZhengZhou HuaWen Chemical Co.Ltd
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Shanghai Gileader Advanced Material Technology Co.,Ltd
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18516111942
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823898732@qq.com
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