ChemicalBook > Product Catalog > Chemical Reagents > Silane reagent > N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Basic information
- Product Name:
- N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
- Synonyms:
-
- Prop-2-en-1-ylbis(trimethylsilyl)amine
- 1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine
- Allylbis(trimethylsilyl)amine
- α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine
- Einecs 231-699-2
- N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
- N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
- 2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&
- CAS:
- 7688-51-9
- MF:
- C9H23NSi2
- MW:
- 201.46
- EINECS:
- 231-699-2
- Product Categories:
-
- Organometallic Reagents
- Organosilicon
- Others
- Mol File:
- 7688-51-9.mol
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N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Chemical Properties
- Boiling point:
- 72 °C/15 mmHg (lit.)
- Density
- 0.816 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.440(lit.)
- Flash point:
- 109 °F
- form
- liquid
- Specific Gravity
- 0.817
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 16-26-36/37
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
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N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Usage And Synthesis
Uses
N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
- Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
- Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
- Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.
AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINESupplier
Meryer (Shanghai) Chemical Technology Co., Ltd.
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BeiJing Hwrk Chemicals Limted
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- 0757-86329057 18934348241
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Shanghai Hanhong Scientific Co.,Ltd.
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- 021-54306202 13764082696;
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ZhengZhou HuaWen Chemical Co.Ltd
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- 0370-2785118 15343847665
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Shanghai Gileader Advanced Material Technology Co.,Ltd
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- 021-69980372 18516111942
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