(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Basic information
- Product Name:
- (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP
- Synonyms:
-
- 4-(2-diphenylphosphanylnaphthalen-1-yl)-N-[(1R)-1-phenylethyl]phthalazin-1-amine
- (R,R)-PINAP
- (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP
- (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine,min.97%(R)-N-PINAP
- (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,R)-N-PINAP
- (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaMine (R,R)-N-PINAP
- (R)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(1R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE
- (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP
- CAS:
- 828927-97-5
- MF:
- C38H30N3P
- MW:
- 559.64
- Product Categories:
-
- Chiral Phosphine
- PINAP Series
- Mol File:
- 828927-97-5.mol
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(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Chemical Properties
- Melting point:
- 185-188°C
- alpha
- +127.3° (c 0.39, CHCl3)
- Boiling point:
- 732.0±60.0 °C(Predicted)
- pka
- 5.35±0.30(Predicted)
- form
- crystal
- color
- colorless
- Sensitive
- air sensitive
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(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Usage And Synthesis
Reactions
- The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
- With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
- With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAPSupplier
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