(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Basic information
- Product Name:
- (R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS
- Synonyms:
-
- (R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS
- (R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene
- (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene
- (R)-Xylyl-PHANEPhos
- (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS
- (R)-XylPhanePHOS
- (R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane
- Phosphine, 1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer
- CAS:
- 325168-89-6
- MF:
- C48H50P2
- MW:
- 688.86
- Product Categories:
-
- PHANEPhos Series
- Chiral Phosphine
- organophosphine ligand
- Mol File:
- 325168-89-6.mol
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(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Chemical Properties
- Melting point:
- 234-238 °C
- Boiling point:
- 785.2±60.0 °C(Predicted)
- form
- Powder
- color
- white
- optical activity
- [α]22/D -61.0, c = 0.1 in ethanol
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(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Usage And Synthesis
Reaction
- Chiral ligand employed in the enantioselective hydrogenation of various ketones.
- Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
- Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
- Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
Uses
Efficient ligand for asymmetric hydrogenation of dehydroamino acids, methyl esters and ketones.
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOSSupplier
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