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Chlorophyllin

Basic information Description References Safety Supplier Related

Chlorophyllin Basic information

Product Name:
Chlorophyllin
Synonyms:
  • ,kappan24)-,trisodium,(sp-4-2-(2s-trans))-
  • [18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl-21H,23H-porphinCuprate(3-)
  • [sp-4-2-(2s-trans)]-
  • 12,17-tetramethyl-21h,23h-porphine-2-propanoato(5-)-kappan21,kappan22,kappan23
  • 17-tetramethyl-21h,23h-porphine-2-propanoato(5-)-n21,n22,n23,n24]-1trisodiu
  • chlorinee6,copperderiv.,trisodiumsalt
  • chlorophyllin,coppersodiumcomplex
  • chlorophyllin,potassium,sodium,andcoppermetallo-complex
CAS:
11006-34-1
MF:
C34H31CuN4NaO6(-2)
MW:
678.18
EINECS:
234-242-5
Product Categories:
  • Organometallics
Mol File:
11006-34-1.mol
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Chlorophyllin Chemical Properties

Melting point:
>300°C
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
DMSO (Slightly), Methanol (Very Slightly)
form 
Solid
color 
Dark Green to Black
Water Solubility 
Soluble in water.
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
LogP
2.170 (est)
EPA Substance Registry System
Cuprate(3-), [(7S,8S)-3-carboxy-5-(carboxymethyl)-13-ethenyl-18-ethyl-7,8-dihydro-2,8,12,17-tetramethyl-21H,23H-porphine-7-propanoato(5-)-.kappa.N21,.kappa.N22,.kappa.N23,.kappa.N24]-, trisodium, (SP-4-2)- (11006-34-1)
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Safety Information

Risk Statements 
62
Safety Statements 
22-24/25
WGK Germany 
2
RTECS 
GS2168866
TSCA 
Yes
HS Code 
32129000
Toxicity
mouse,LD50,intraperitoneal,190mg/kg (190mg/kg),Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 43, Pg. 722, 1954.

MSDS

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Chlorophyllin Usage And Synthesis

Description

Chlorophyllin are a group of water-soluble salts being semi-synthetic derivative of chlorophyll. Its major form sodium/copper derivative can be used as a food additive and in alternative medicine. As alternative medicine, it can be used as an aid to reduce the odor of urines or feces (bowel movements). It can also be used to improve the life quality in people who have fecal incontinence due to spinal cord injury, bowel cancer, psychotic disorder, terminal illness, or other disorders. It can also be sold as an herbal supplement. Chlorophyllin can also bind to mutagenic substances such as polycyclic aromatic benzo[a]pyrene and dibenzo{a,i}pyrene. As a topical preparation, it is useful for both treatment and odor control of wounds, injuries, and other skin conditions such as radiation burns. 

References

https://en.wikipedia.org/wiki/Chlorophyllin
http://www.everydayhealth.com/drugs/chlorophyllin

Chemical Properties

Dark green solid

Uses

Chlorophyllin, coppered trisodium salt is used in the spectrophotometric determination of Ven- lafaxine hydrochloride. A hybrid photoelectrochemical biofuel cell is composed of a TiO 2 film conductive glass electrode sensitized by a copper chlorophyll trisodium salt. Visible light-sensitive gels were prepared by introducing a chromophore (trisodium salt of copper chlorophyllin) to thermosensitive gels.

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