TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE Chemical Properties

Melting point:

93-98 °C(lit.)

storage temp. 

2-8°C

solubility 

slightly sol. in dichloromethane

form 

powder to crystal

color 

White to Almost white

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

BRN 

8238791

InChIKey

LCFZZOGKVOTFPU-UHFFFAOYSA-N

Safety Information

Hazard Codes 

F,Xi

Risk Statements 

15-36/37/38

Safety Statements 

26-36-43

RIDADR 

UN 2813 4.3/PG 2

WGK Germany 

3

F 

3-10-21

HazardClass 

4.3

PackingGroup 

III

HS Code 

29239000

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE Usage And Synthesis

Uses

Selective reducing agent.

reaction suitability

reagent type: reductant

Synthesis

Tetramethylammonium Triacetoxyborohydride is synthesized by:

storage

Tetramethylammonium triacetoxyborohydride is moisture sensitive; irritant. Stable at 25 °C. Handle in a well ventilated fume hood.

Purification Methods

If impure, wash it with freshly distilled Et2O and dry it overnight in a vacuum to give a free flowing powder. Check 1H NMR, and if still suspect prepare it freshly from Me4NBH4 and AcOH in *C6H6 and store it away from moisture [Banus et al. J Am Chem Soc 74 2346 1952, Evans & Chipman Tetrahedron Lett 27 5939 1986]. Itisan IRRITANT and MOISTURE SENSITIVE.

TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE(109704-53-2)Related Product Information

• N,N,N',N'-TETRAMETHYLDIAMINOMETHANE
• Triisopropylsilyl chloride
• Triethylsilane
• FLUOROTRIETHYLSILANE
• TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE
• Chlorotriethylsilane
• Sodium triacetoxyborohydride
• Tetramethylammonium acetate
• Triethyl borate
• Orthoboric acid
• Tetramethylammonium borohydride
• Trimethyl borate
• TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE